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1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocadmate(II).

Zhang Y, Zhu BH - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title salt, (C(8)H(15)N(3))[CdCl(4)], four Cl atoms coordinate the Cd(II) atom in a slightly distorted tetra-hedral geometry.In the crystal, each [CdCl(4)](2-) anion is connected to the 1-cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane dications by N-H⋯Cl hydrogen bonds, forming chains parallel to [001].C-H⋯Cl inter-actions also occur.

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Affiliation: Ordered Matter Science Research Center, Southeast University, Nanjing 211189, People's Republic of China.

ABSTRACT
In the title salt, (C(8)H(15)N(3))[CdCl(4)], four Cl atoms coordinate the Cd(II) atom in a slightly distorted tetra-hedral geometry. In the crystal, each [CdCl(4)](2-) anion is connected to the 1-cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane dications by N-H⋯Cl hydrogen bonds, forming chains parallel to [001]. C-H⋯Cl inter-actions also occur.

No MeSH data available.


A view of the N—H···Cl hydrogen bonds (dotted lines) in the crystal structure of the title compound. H atoms non-participating in hydrogen-bonding were omitted for clarity.
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Fap2: A view of the N—H···Cl hydrogen bonds (dotted lines) in the crystal structure of the title compound. H atoms non-participating in hydrogen-bonding were omitted for clarity.


1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocadmate(II).

Zhang Y, Zhu BH - Acta Crystallogr Sect E Struct Rep Online (2012)

A view of the N—H···Cl hydrogen bonds (dotted lines) in the crystal structure of the title compound. H atoms non-participating in hydrogen-bonding were omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344406&req=5

Fap2: A view of the N—H···Cl hydrogen bonds (dotted lines) in the crystal structure of the title compound. H atoms non-participating in hydrogen-bonding were omitted for clarity.
Bottom Line: In the title salt, (C(8)H(15)N(3))[CdCl(4)], four Cl atoms coordinate the Cd(II) atom in a slightly distorted tetra-hedral geometry.In the crystal, each [CdCl(4)](2-) anion is connected to the 1-cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane dications by N-H⋯Cl hydrogen bonds, forming chains parallel to [001].C-H⋯Cl inter-actions also occur.

View Article: PubMed Central - HTML - PubMed

Affiliation: Ordered Matter Science Research Center, Southeast University, Nanjing 211189, People's Republic of China.

ABSTRACT
In the title salt, (C(8)H(15)N(3))[CdCl(4)], four Cl atoms coordinate the Cd(II) atom in a slightly distorted tetra-hedral geometry. In the crystal, each [CdCl(4)](2-) anion is connected to the 1-cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane dications by N-H⋯Cl hydrogen bonds, forming chains parallel to [001]. C-H⋯Cl inter-actions also occur.

No MeSH data available.