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Bis(2-amino-benzothia-zol-3-ium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-κ(3)O(2),O(3),O(7))zincate hexa-hydrate.

Zhang F, Lv TX, Feng J, Lin QY - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title hydrated mol-ecular salt, (C(7)H(7)N(2)S)(2)[Zn(C(8)H(8)O(5))(2)]·6H(2)O, which is isotypic with its Mn(II), Co(II) and Ni(II) analogues, the Zn(2+) ion lies on a crystallographic inversion centre and a distorted ZnO(6) octa-hedral coordination geometry arises from the two doubly deprotonated O,O',O''-tridentate ligands.In the crystal, the components are linked by N-H⋯O(a), N-H⋯O(w), O(w)-H⋯O(a) and O(w)-H⋯O(w) hydrogen bonds (w = water and a = anion).

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ABSTRACT
In the title hydrated mol-ecular salt, (C(7)H(7)N(2)S)(2)[Zn(C(8)H(8)O(5))(2)]·6H(2)O, which is isotypic with its Mn(II), Co(II) and Ni(II) analogues, the Zn(2+) ion lies on a crystallographic inversion centre and a distorted ZnO(6) octa-hedral coordination geometry arises from the two doubly deprotonated O,O',O''-tridentate ligands. In the crystal, the components are linked by N-H⋯O(a), N-H⋯O(w), O(w)-H⋯O(a) and O(w)-H⋯O(w) hydrogen bonds (w = water and a = anion).

No MeSH data available.


Related in: MedlinePlus

A view of (I) showing displacement ellipsoids drawn at the 30% probability level. Atoms with label suffix A are generatd by (1–x, –y, –z).
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Fap1: A view of (I) showing displacement ellipsoids drawn at the 30% probability level. Atoms with label suffix A are generatd by (1–x, –y, –z).


Bis(2-amino-benzothia-zol-3-ium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-κ(3)O(2),O(3),O(7))zincate hexa-hydrate.

Zhang F, Lv TX, Feng J, Lin QY - Acta Crystallogr Sect E Struct Rep Online (2012)

A view of (I) showing displacement ellipsoids drawn at the 30% probability level. Atoms with label suffix A are generatd by (1–x, –y, –z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344404&req=5

Fap1: A view of (I) showing displacement ellipsoids drawn at the 30% probability level. Atoms with label suffix A are generatd by (1–x, –y, –z).
Bottom Line: In the title hydrated mol-ecular salt, (C(7)H(7)N(2)S)(2)[Zn(C(8)H(8)O(5))(2)]·6H(2)O, which is isotypic with its Mn(II), Co(II) and Ni(II) analogues, the Zn(2+) ion lies on a crystallographic inversion centre and a distorted ZnO(6) octa-hedral coordination geometry arises from the two doubly deprotonated O,O',O''-tridentate ligands.In the crystal, the components are linked by N-H⋯O(a), N-H⋯O(w), O(w)-H⋯O(a) and O(w)-H⋯O(w) hydrogen bonds (w = water and a = anion).

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title hydrated mol-ecular salt, (C(7)H(7)N(2)S)(2)[Zn(C(8)H(8)O(5))(2)]·6H(2)O, which is isotypic with its Mn(II), Co(II) and Ni(II) analogues, the Zn(2+) ion lies on a crystallographic inversion centre and a distorted ZnO(6) octa-hedral coordination geometry arises from the two doubly deprotonated O,O',O''-tridentate ligands. In the crystal, the components are linked by N-H⋯O(a), N-H⋯O(w), O(w)-H⋯O(a) and O(w)-H⋯O(w) hydrogen bonds (w = water and a = anion).

No MeSH data available.


Related in: MedlinePlus