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N-Benzyl-N,N-dimethyl-octa-decan-1-aminium (2-thioxo-1,3-dithiole-4,5-dithiol-ato-κ(2)S(4),S(5))nickelate(III).

Liu GX - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The C(18) chains in both cations adopt almost ideal extended conformations.The Ni(III) atoms are coordinated by two S,S'-bidentate ligands, generating NiS(4) square planes.Short Ni⋯S [3.734 (2) Å] and S⋯S contacts [3.5438 (15) Å] occur in the crystal structure; if these are considered to be bonding inter-actions, then infinite sheets of anions parallel to (111) arise.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Biochemical and Environmental Engineering, Nanjing Xiaozhuang University, Nanjing 211171, People's Republic of China.

ABSTRACT
The asymmtric unit of the title compound, (C(27)H(50)N)[Ni(C(3)S(5))(2)], contains two N-benzyl-N,N-dimethyl-octa-decan-1-aminium cations, [BDA](+), and two [Ni(dmit)(2)](-) anions (dmit = 2-thioxo-1,3-dithiole-4,5-dithiol-ate). The C(18) chains in both cations adopt almost ideal extended conformations. The Ni(III) atoms are coordinated by two S,S'-bidentate ligands, generating NiS(4) square planes. Short Ni⋯S [3.734 (2) Å] and S⋯S contacts [3.5438 (15) Å] occur in the crystal structure; if these are considered to be bonding inter-actions, then infinite sheets of anions parallel to (111) arise.

No MeSH data available.


Related in: MedlinePlus

The packing of the [Ni(dmit)2]- anions of (I), showing the S···S and Ni···S contacts as dashed lines.
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Fap2: The packing of the [Ni(dmit)2]- anions of (I), showing the S···S and Ni···S contacts as dashed lines.


N-Benzyl-N,N-dimethyl-octa-decan-1-aminium (2-thioxo-1,3-dithiole-4,5-dithiol-ato-κ(2)S(4),S(5))nickelate(III).

Liu GX - Acta Crystallogr Sect E Struct Rep Online (2012)

The packing of the [Ni(dmit)2]- anions of (I), showing the S···S and Ni···S contacts as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344399&req=5

Fap2: The packing of the [Ni(dmit)2]- anions of (I), showing the S···S and Ni···S contacts as dashed lines.
Bottom Line: The C(18) chains in both cations adopt almost ideal extended conformations.The Ni(III) atoms are coordinated by two S,S'-bidentate ligands, generating NiS(4) square planes.Short Ni⋯S [3.734 (2) Å] and S⋯S contacts [3.5438 (15) Å] occur in the crystal structure; if these are considered to be bonding inter-actions, then infinite sheets of anions parallel to (111) arise.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Biochemical and Environmental Engineering, Nanjing Xiaozhuang University, Nanjing 211171, People's Republic of China.

ABSTRACT
The asymmtric unit of the title compound, (C(27)H(50)N)[Ni(C(3)S(5))(2)], contains two N-benzyl-N,N-dimethyl-octa-decan-1-aminium cations, [BDA](+), and two [Ni(dmit)(2)](-) anions (dmit = 2-thioxo-1,3-dithiole-4,5-dithiol-ate). The C(18) chains in both cations adopt almost ideal extended conformations. The Ni(III) atoms are coordinated by two S,S'-bidentate ligands, generating NiS(4) square planes. Short Ni⋯S [3.734 (2) Å] and S⋯S contacts [3.5438 (15) Å] occur in the crystal structure; if these are considered to be bonding inter-actions, then infinite sheets of anions parallel to (111) arise.

No MeSH data available.


Related in: MedlinePlus