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(2,2'-Bipyrimidine-κ(2)N(1),N(1'))bis-(thio-cyanato-κN)platinum(II).

Ha K - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The thio-cyanate ligands are almost linear, displaying N-C-S bond angles of 178.6 (11) and 173.7 (11)°, and the N atoms are slightly bent coordinated to the Pt atom with Pt-N-C bond angles of 172.7 (9) and 160.4 (10)°.In the crystal, mol-ecules are held together by C-H⋯S hydrogen bonds.Intra-molecular C-H⋯N hydrogen bonds are also observed.

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Affiliation: School of Applied Chemical Engineering, The Research Institute of Catalysis, Chonnam National University, Gwangju 500-757, Republic of Korea.

ABSTRACT
In the title complex, [Pt(NCS)(2)(C(8)H(6)N(4))], the Pt(II) ion is four-coordinated in a distorted square-planar environment defined by two pyrimidine N atoms derived from a chelating 2,2'-bipyrimidine (bpym) ligand and two mutually cis N atoms from two SCN(-) anions. The thio-cyanate ligands are almost linear, displaying N-C-S bond angles of 178.6 (11) and 173.7 (11)°, and the N atoms are slightly bent coordinated to the Pt atom with Pt-N-C bond angles of 172.7 (9) and 160.4 (10)°. In the crystal, mol-ecules are held together by C-H⋯S hydrogen bonds. Intra-molecular C-H⋯N hydrogen bonds are also observed.

No MeSH data available.


The molecular structure of the title complex, with atom numbering. Displacement ellipsoids are drawn at the 50% probability level for non-H atoms.
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Fap1: The molecular structure of the title complex, with atom numbering. Displacement ellipsoids are drawn at the 50% probability level for non-H atoms.


(2,2'-Bipyrimidine-κ(2)N(1),N(1'))bis-(thio-cyanato-κN)platinum(II).

Ha K - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the title complex, with atom numbering. Displacement ellipsoids are drawn at the 50% probability level for non-H atoms.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344397&req=5

Fap1: The molecular structure of the title complex, with atom numbering. Displacement ellipsoids are drawn at the 50% probability level for non-H atoms.
Bottom Line: The thio-cyanate ligands are almost linear, displaying N-C-S bond angles of 178.6 (11) and 173.7 (11)°, and the N atoms are slightly bent coordinated to the Pt atom with Pt-N-C bond angles of 172.7 (9) and 160.4 (10)°.In the crystal, mol-ecules are held together by C-H⋯S hydrogen bonds.Intra-molecular C-H⋯N hydrogen bonds are also observed.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Applied Chemical Engineering, The Research Institute of Catalysis, Chonnam National University, Gwangju 500-757, Republic of Korea.

ABSTRACT
In the title complex, [Pt(NCS)(2)(C(8)H(6)N(4))], the Pt(II) ion is four-coordinated in a distorted square-planar environment defined by two pyrimidine N atoms derived from a chelating 2,2'-bipyrimidine (bpym) ligand and two mutually cis N atoms from two SCN(-) anions. The thio-cyanate ligands are almost linear, displaying N-C-S bond angles of 178.6 (11) and 173.7 (11)°, and the N atoms are slightly bent coordinated to the Pt atom with Pt-N-C bond angles of 172.7 (9) and 160.4 (10)°. In the crystal, mol-ecules are held together by C-H⋯S hydrogen bonds. Intra-molecular C-H⋯N hydrogen bonds are also observed.

No MeSH data available.