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Bis(2-methyl-piperidinium) penta-chlorido-anti-monate(III).

Xu Q - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the [SbCl(5)](2-) unit, the Sb(III) ion is coordinated by five chloride anions [Sb-Cl = 2.3721 (11)-2.6656 (12) Å] in a distorted square-pyramidal geometry.However, one chloride anion from a neighbouring [SbCl(5)](2-) unit provides a short Sb⋯Cl contact of 3.3600 (12) Å and completes the Sb coordination environment up to an elongated octa-hedron.In the crystal, N-H⋯Cl hydrogen bonds link cations and anions into columns propagating along [100].

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Affiliation: Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China.

ABSTRACT
The asymmetric unit of the title compound, (C(6)H(14)N)(2)[SbCl(5)], contains one cation and half of the anion on a special position (specifically, the Sb(III) ion and three chloride anions are situated on a mirror plane). In the [SbCl(5)](2-) unit, the Sb(III) ion is coordinated by five chloride anions [Sb-Cl = 2.3721 (11)-2.6656 (12) Å] in a distorted square-pyramidal geometry. However, one chloride anion from a neighbouring [SbCl(5)](2-) unit provides a short Sb⋯Cl contact of 3.3600 (12) Å and completes the Sb coordination environment up to an elongated octa-hedron. In the crystal, N-H⋯Cl hydrogen bonds link cations and anions into columns propagating along [100].

No MeSH data available.


A portion of the packing diagram with hydrogen bonds shown as dashed lines.
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Fap2: A portion of the packing diagram with hydrogen bonds shown as dashed lines.


Bis(2-methyl-piperidinium) penta-chlorido-anti-monate(III).

Xu Q - Acta Crystallogr Sect E Struct Rep Online (2012)

A portion of the packing diagram with hydrogen bonds shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344392&req=5

Fap2: A portion of the packing diagram with hydrogen bonds shown as dashed lines.
Bottom Line: In the [SbCl(5)](2-) unit, the Sb(III) ion is coordinated by five chloride anions [Sb-Cl = 2.3721 (11)-2.6656 (12) Å] in a distorted square-pyramidal geometry.However, one chloride anion from a neighbouring [SbCl(5)](2-) unit provides a short Sb⋯Cl contact of 3.3600 (12) Å and completes the Sb coordination environment up to an elongated octa-hedron.In the crystal, N-H⋯Cl hydrogen bonds link cations and anions into columns propagating along [100].

View Article: PubMed Central - HTML - PubMed

Affiliation: Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China.

ABSTRACT
The asymmetric unit of the title compound, (C(6)H(14)N)(2)[SbCl(5)], contains one cation and half of the anion on a special position (specifically, the Sb(III) ion and three chloride anions are situated on a mirror plane). In the [SbCl(5)](2-) unit, the Sb(III) ion is coordinated by five chloride anions [Sb-Cl = 2.3721 (11)-2.6656 (12) Å] in a distorted square-pyramidal geometry. However, one chloride anion from a neighbouring [SbCl(5)](2-) unit provides a short Sb⋯Cl contact of 3.3600 (12) Å and completes the Sb coordination environment up to an elongated octa-hedron. In the crystal, N-H⋯Cl hydrogen bonds link cations and anions into columns propagating along [100].

No MeSH data available.