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Bis{S-benzyl 3-[(6-methyl-pyridin-2-yl)methyl-idene]dithio-carbazato}nickel(II).

Ravoof TB, Omar SA, Mohamed Tahir MI, Crouse KA - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The asymmetric unit of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)], consists of two independent mol-ecules with similar configurations.Each Ni(2+) cation is coordinated in a cis-mode by two tridentate N,N',S-chelating Schiff base ligands, creating a distorted octa-hedron [the smallest angle being 77.57 (7)° and the widest being 168.97 (7)° for one mol-ecule, and 78.04 (7) and 167.55 (7)° for the second mol-ecule].The dihedral angle between the mean coordination planes of the two ligands is 86.76 (7)° for one and 89.99 (7)° for the second mol-ecule. π-π inter-actions between neighbouring pyridine rings with plane-to-plane distances of 3.540 (1) and 3.704 (1) Å are observed.

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Affiliation: Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM, Serdang, Selangor, Malaysia.

ABSTRACT
The asymmetric unit of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)], consists of two independent mol-ecules with similar configurations. Each Ni(2+) cation is coordinated in a cis-mode by two tridentate N,N',S-chelating Schiff base ligands, creating a distorted octa-hedron [the smallest angle being 77.57 (7)° and the widest being 168.97 (7)° for one mol-ecule, and 78.04 (7) and 167.55 (7)° for the second mol-ecule]. The dihedral angle between the mean coordination planes of the two ligands is 86.76 (7)° for one and 89.99 (7)° for the second mol-ecule. π-π inter-actions between neighbouring pyridine rings with plane-to-plane distances of 3.540 (1) and 3.704 (1) Å are observed.

No MeSH data available.


Molecular packing diagram of the title compound viewed along the a axis. Hydrogen atoms are omitted for clarity.
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Fap2: Molecular packing diagram of the title compound viewed along the a axis. Hydrogen atoms are omitted for clarity.


Bis{S-benzyl 3-[(6-methyl-pyridin-2-yl)methyl-idene]dithio-carbazato}nickel(II).

Ravoof TB, Omar SA, Mohamed Tahir MI, Crouse KA - Acta Crystallogr Sect E Struct Rep Online (2012)

Molecular packing diagram of the title compound viewed along the a axis. Hydrogen atoms are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344386&req=5

Fap2: Molecular packing diagram of the title compound viewed along the a axis. Hydrogen atoms are omitted for clarity.
Bottom Line: The asymmetric unit of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)], consists of two independent mol-ecules with similar configurations.Each Ni(2+) cation is coordinated in a cis-mode by two tridentate N,N',S-chelating Schiff base ligands, creating a distorted octa-hedron [the smallest angle being 77.57 (7)° and the widest being 168.97 (7)° for one mol-ecule, and 78.04 (7) and 167.55 (7)° for the second mol-ecule].The dihedral angle between the mean coordination planes of the two ligands is 86.76 (7)° for one and 89.99 (7)° for the second mol-ecule. π-π inter-actions between neighbouring pyridine rings with plane-to-plane distances of 3.540 (1) and 3.704 (1) Å are observed.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM, Serdang, Selangor, Malaysia.

ABSTRACT
The asymmetric unit of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)], consists of two independent mol-ecules with similar configurations. Each Ni(2+) cation is coordinated in a cis-mode by two tridentate N,N',S-chelating Schiff base ligands, creating a distorted octa-hedron [the smallest angle being 77.57 (7)° and the widest being 168.97 (7)° for one mol-ecule, and 78.04 (7) and 167.55 (7)° for the second mol-ecule]. The dihedral angle between the mean coordination planes of the two ligands is 86.76 (7)° for one and 89.99 (7)° for the second mol-ecule. π-π inter-actions between neighbouring pyridine rings with plane-to-plane distances of 3.540 (1) and 3.704 (1) Å are observed.

No MeSH data available.