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Dichloridobis(4-pyridylmethyl 1H-pyrrole-2-carboxyl-ate-κN)zinc.

Li C, Zhang G, Yin Z - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The dihedral angle between the two pyridine rings is 54.8 (3)°.The complex mol-ecules are connected into chains extending along [101] by N-H⋯Cl hydrogen bonds.The chains are further assembled into (-101) layers by C-H⋯O and C-H⋯Cl inter-actions.

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ABSTRACT
In the title mol-ecule, [ZnCl(2)(C(11)H(10)N(2)O(2))(2)], the Zn(II) ion, situated on a twofold axis, is in a distorted tetra-hedral coordination environment formed by two chloride anions and two pyridine N atoms of the two organic ligands. In the pyrrole-2-carboxyl-ate unit, the pyrrole N-H group and the carbonyl group point approximately in the same direction. The dihedral angle between the two pyridine rings is 54.8 (3)°. The complex mol-ecules are connected into chains extending along [101] by N-H⋯Cl hydrogen bonds. The chains are further assembled into (-101) layers by C-H⋯O and C-H⋯Cl inter-actions.

No MeSH data available.


The molecular structure of the title compound with displacement ellipsoids shown at the 30% probability level. The atom with the 'A' label were generated by the symmetry operation -x,y,1/2-z.
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Fap1: The molecular structure of the title compound with displacement ellipsoids shown at the 30% probability level. The atom with the 'A' label were generated by the symmetry operation -x,y,1/2-z.


Dichloridobis(4-pyridylmethyl 1H-pyrrole-2-carboxyl-ate-κN)zinc.

Li C, Zhang G, Yin Z - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the title compound with displacement ellipsoids shown at the 30% probability level. The atom with the 'A' label were generated by the symmetry operation -x,y,1/2-z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3297270&req=5

Fap1: The molecular structure of the title compound with displacement ellipsoids shown at the 30% probability level. The atom with the 'A' label were generated by the symmetry operation -x,y,1/2-z.
Bottom Line: The dihedral angle between the two pyridine rings is 54.8 (3)°.The complex mol-ecules are connected into chains extending along [101] by N-H⋯Cl hydrogen bonds.The chains are further assembled into (-101) layers by C-H⋯O and C-H⋯Cl inter-actions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title mol-ecule, [ZnCl(2)(C(11)H(10)N(2)O(2))(2)], the Zn(II) ion, situated on a twofold axis, is in a distorted tetra-hedral coordination environment formed by two chloride anions and two pyridine N atoms of the two organic ligands. In the pyrrole-2-carboxyl-ate unit, the pyrrole N-H group and the carbonyl group point approximately in the same direction. The dihedral angle between the two pyridine rings is 54.8 (3)°. The complex mol-ecules are connected into chains extending along [101] by N-H⋯Cl hydrogen bonds. The chains are further assembled into (-101) layers by C-H⋯O and C-H⋯Cl inter-actions.

No MeSH data available.