Limits...
(2,2'-Bipyridine-κN,N')bis-(4-chloro-benzoato-κO)zinc.

Zhang BS, Zhu HL, Li J, Dai DD, Peng YB - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The Zn(II) atom is located on a twofold rotation axis, which also passes through the mid-point of the central C-C bond of the bpy ligand.In the crystal, weak C-H⋯O hydrogen bonds and π-π stacking inter-actions between the pyridine rings of the bpy ligands [centroid-centroid distance = 3.642 (3) Å] link the complex mol-ecules into a two-dimensional supra-molecular structure parallel to (100).An intra-molecular C-H⋯O hydrogen bond is also observed.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Zn(C(7)H(4)ClO(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by two O atoms from two 4-chloro-benzoate ligands and two N atoms from a chelating 2,2'-bipyridine (bpy) mol-ecule in a distorted N(2)O(2) tetra-hedral geometry. The Zn(II) atom is located on a twofold rotation axis, which also passes through the mid-point of the central C-C bond of the bpy ligand. In the crystal, weak C-H⋯O hydrogen bonds and π-π stacking inter-actions between the pyridine rings of the bpy ligands [centroid-centroid distance = 3.642 (3) Å] link the complex mol-ecules into a two-dimensional supra-molecular structure parallel to (100). An intra-molecular C-H⋯O hydrogen bond is also observed.

No MeSH data available.


A view of the crystal packing, showing π–π interactions (dashed double arrows), with a centroid–centroid distance of 3.642 (3) Å, and C—H···O hydrogen bonds (dashed lines).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3297269&req=5

Fap2: A view of the crystal packing, showing π–π interactions (dashed double arrows), with a centroid–centroid distance of 3.642 (3) Å, and C—H···O hydrogen bonds (dashed lines).


(2,2'-Bipyridine-κN,N')bis-(4-chloro-benzoato-κO)zinc.

Zhang BS, Zhu HL, Li J, Dai DD, Peng YB - Acta Crystallogr Sect E Struct Rep Online (2012)

A view of the crystal packing, showing π–π interactions (dashed double arrows), with a centroid–centroid distance of 3.642 (3) Å, and C—H···O hydrogen bonds (dashed lines).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3297269&req=5

Fap2: A view of the crystal packing, showing π–π interactions (dashed double arrows), with a centroid–centroid distance of 3.642 (3) Å, and C—H···O hydrogen bonds (dashed lines).
Bottom Line: The Zn(II) atom is located on a twofold rotation axis, which also passes through the mid-point of the central C-C bond of the bpy ligand.In the crystal, weak C-H⋯O hydrogen bonds and π-π stacking inter-actions between the pyridine rings of the bpy ligands [centroid-centroid distance = 3.642 (3) Å] link the complex mol-ecules into a two-dimensional supra-molecular structure parallel to (100).An intra-molecular C-H⋯O hydrogen bond is also observed.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Zn(C(7)H(4)ClO(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by two O atoms from two 4-chloro-benzoate ligands and two N atoms from a chelating 2,2'-bipyridine (bpy) mol-ecule in a distorted N(2)O(2) tetra-hedral geometry. The Zn(II) atom is located on a twofold rotation axis, which also passes through the mid-point of the central C-C bond of the bpy ligand. In the crystal, weak C-H⋯O hydrogen bonds and π-π stacking inter-actions between the pyridine rings of the bpy ligands [centroid-centroid distance = 3.642 (3) Å] link the complex mol-ecules into a two-dimensional supra-molecular structure parallel to (100). An intra-molecular C-H⋯O hydrogen bond is also observed.

No MeSH data available.