Limits...
2,4,5-Trichloro-anilinium perchlorate 18-crown-6 clathrate.

Xu J - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, C(6)H(5)Cl(3)N(+)·ClO(4) (-)·C(12)H(24)O(6), the perchlorate anion is disordered over two orientations in a 0.666 (17):0.334 (17) ratio.The ammonium group of the organic cation inserts into the crown ether ring and forms three bifurcated N-H⋯(O,O) hydrogen bonds to generate a supra-molecular complex.The macrocycle has approximate D(3d) local symmetry.

View Article: PubMed Central - HTML - PubMed

Affiliation: Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.

ABSTRACT
In the title compound, C(6)H(5)Cl(3)N(+)·ClO(4) (-)·C(12)H(24)O(6), the perchlorate anion is disordered over two orientations in a 0.666 (17):0.334 (17) ratio. The ammonium group of the organic cation inserts into the crown ether ring and forms three bifurcated N-H⋯(O,O) hydrogen bonds to generate a supra-molecular complex. The macrocycle has approximate D(3d) local symmetry.

No MeSH data available.


Related in: MedlinePlus

The crystal packing of the title compound, showing the H-bonding interactions. H atoms not involved in hydrogen bonding (dashed line) have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3295508&req=5

Fap2: The crystal packing of the title compound, showing the H-bonding interactions. H atoms not involved in hydrogen bonding (dashed line) have been omitted for clarity.


2,4,5-Trichloro-anilinium perchlorate 18-crown-6 clathrate.

Xu J - Acta Crystallogr Sect E Struct Rep Online (2012)

The crystal packing of the title compound, showing the H-bonding interactions. H atoms not involved in hydrogen bonding (dashed line) have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3295508&req=5

Fap2: The crystal packing of the title compound, showing the H-bonding interactions. H atoms not involved in hydrogen bonding (dashed line) have been omitted for clarity.
Bottom Line: In the title compound, C(6)H(5)Cl(3)N(+)·ClO(4) (-)·C(12)H(24)O(6), the perchlorate anion is disordered over two orientations in a 0.666 (17):0.334 (17) ratio.The ammonium group of the organic cation inserts into the crown ether ring and forms three bifurcated N-H⋯(O,O) hydrogen bonds to generate a supra-molecular complex.The macrocycle has approximate D(3d) local symmetry.

View Article: PubMed Central - HTML - PubMed

Affiliation: Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.

ABSTRACT
In the title compound, C(6)H(5)Cl(3)N(+)·ClO(4) (-)·C(12)H(24)O(6), the perchlorate anion is disordered over two orientations in a 0.666 (17):0.334 (17) ratio. The ammonium group of the organic cation inserts into the crown ether ring and forms three bifurcated N-H⋯(O,O) hydrogen bonds to generate a supra-molecular complex. The macrocycle has approximate D(3d) local symmetry.

No MeSH data available.


Related in: MedlinePlus