Limits...
Dicyclo-hex-yl(4-isopropyl-phen-yl)phosphane selenide.

Makhoba S, Muller A, Phasha Z - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: Both cyclo-hexyl groups adopt chair conformations.A cone angle of 170° was calculated using an adaptation of the Tolman model.Inter-molecular C-H⋯Se and C-H⋯Cg contacts are observed (Cg is the centroid of the benzene ring).

View Article: PubMed Central - HTML - PubMed

Affiliation: Research Center for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524, Auckland Park, Johannesburg 2006, South Africa.

ABSTRACT
In the title compund, C(21)H(33)PSe, the Se=P bond is part of a distorted tetra-hedral environment on the P atom. Both cyclo-hexyl groups adopt chair conformations. A cone angle of 170° was calculated using an adaptation of the Tolman model. Inter-molecular C-H⋯Se and C-H⋯Cg contacts are observed (Cg is the centroid of the benzene ring).

No MeSH data available.


Packing diagram showing the interactions observed for the structure.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3295440&req=5

Fap2: Packing diagram showing the interactions observed for the structure.


Dicyclo-hex-yl(4-isopropyl-phen-yl)phosphane selenide.

Makhoba S, Muller A, Phasha Z - Acta Crystallogr Sect E Struct Rep Online (2012)

Packing diagram showing the interactions observed for the structure.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3295440&req=5

Fap2: Packing diagram showing the interactions observed for the structure.
Bottom Line: Both cyclo-hexyl groups adopt chair conformations.A cone angle of 170° was calculated using an adaptation of the Tolman model.Inter-molecular C-H⋯Se and C-H⋯Cg contacts are observed (Cg is the centroid of the benzene ring).

View Article: PubMed Central - HTML - PubMed

Affiliation: Research Center for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524, Auckland Park, Johannesburg 2006, South Africa.

ABSTRACT
In the title compund, C(21)H(33)PSe, the Se=P bond is part of a distorted tetra-hedral environment on the P atom. Both cyclo-hexyl groups adopt chair conformations. A cone angle of 170° was calculated using an adaptation of the Tolman model. Inter-molecular C-H⋯Se and C-H⋯Cg contacts are observed (Cg is the centroid of the benzene ring).

No MeSH data available.