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4,5-Diiodo-2-phenyl-1H-imidazole.

Chlupatý T, Pařík P, Padělková Z - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The structure of the title compound, C(9)H(6)I(2)N(2), contains two symmetry-independent mol-ecules.The inter-planar angles between the imidazole and phenyl ring planes are 16.35 (3) and 17.48 (6)°.The title compound is the first example of a structurally characterized 4,5-diiodo-imidazole with an organic substituent in the 2-position and without protection on the N-H group of imidazole.

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ABSTRACT
The structure of the title compound, C(9)H(6)I(2)N(2), contains two symmetry-independent mol-ecules. The inter-planar angles between the imidazole and phenyl ring planes are 16.35 (3) and 17.48 (6)°. Mol-ecules are connected via N-H⋯N hydrogen bonds to form zigzag chains along the b axis. The title compound is the first example of a structurally characterized 4,5-diiodo-imidazole with an organic substituent in the 2-position and without protection on the N-H group of imidazole.

No MeSH data available.


Related in: MedlinePlus

View of the crystal structure down the c axis showing the hydrogen bond interactions.
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Fap2: View of the crystal structure down the c axis showing the hydrogen bond interactions.


4,5-Diiodo-2-phenyl-1H-imidazole.

Chlupatý T, Pařík P, Padělková Z - Acta Crystallogr Sect E Struct Rep Online (2012)

View of the crystal structure down the c axis showing the hydrogen bond interactions.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3275288&req=5

Fap2: View of the crystal structure down the c axis showing the hydrogen bond interactions.
Bottom Line: The structure of the title compound, C(9)H(6)I(2)N(2), contains two symmetry-independent mol-ecules.The inter-planar angles between the imidazole and phenyl ring planes are 16.35 (3) and 17.48 (6)°.The title compound is the first example of a structurally characterized 4,5-diiodo-imidazole with an organic substituent in the 2-position and without protection on the N-H group of imidazole.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The structure of the title compound, C(9)H(6)I(2)N(2), contains two symmetry-independent mol-ecules. The inter-planar angles between the imidazole and phenyl ring planes are 16.35 (3) and 17.48 (6)°. Mol-ecules are connected via N-H⋯N hydrogen bonds to form zigzag chains along the b axis. The title compound is the first example of a structurally characterized 4,5-diiodo-imidazole with an organic substituent in the 2-position and without protection on the N-H group of imidazole.

No MeSH data available.


Related in: MedlinePlus