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Methyl (2Z)-2-({N-[2-(hy-droxy-meth-yl)phen-yl]-4-methyl-benzene-sulfonamido}-meth-yl)-3-phenyl-prop-2-enoate.

Madhanraj R, Murugavel S, Kannan D, Bakthadoss M - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, C(25)H(25)NO(5)S, the O atom of the hy-droxy group is disordered over two positions, with occupancies of 0.820 (2) and 0.180 (2).The sulfonyl-bound benzene ring forms dihedral angles of 31.8 (1) and 60.7 (1)°, respectively, with the hy-droxy-methyl-benzene and phenyl rings.The crystal packing is stabilized by inter-molecular C-H⋯O hydrogen bonds and C-H⋯π inter-actions.

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ABSTRACT
In the title compound, C(25)H(25)NO(5)S, the O atom of the hy-droxy group is disordered over two positions, with occupancies of 0.820 (2) and 0.180 (2). The sulfonyl-bound benzene ring forms dihedral angles of 31.8 (1) and 60.7 (1)°, respectively, with the hy-droxy-methyl-benzene and phenyl rings. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯O hydrogen bond, generating an S(8) ring motif. The crystal packing is stabilized by inter-molecular C-H⋯O hydrogen bonds and C-H⋯π inter-actions.

No MeSH data available.


Related in: MedlinePlus

A view of the C—H···π interactions, in the crystal structure of the title compound. Cg1 and Cg2 are the centroids of the (C18–C23) benzene and (C8–C13) benzene rings, respectively. [Symmetry code: (iii) x, 1+y, z; (iv) -x, 1-y, -z.]
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Fap4: A view of the C—H···π interactions, in the crystal structure of the title compound. Cg1 and Cg2 are the centroids of the (C18–C23) benzene and (C8–C13) benzene rings, respectively. [Symmetry code: (iii) x, 1+y, z; (iv) -x, 1-y, -z.]


Methyl (2Z)-2-({N-[2-(hy-droxy-meth-yl)phen-yl]-4-methyl-benzene-sulfonamido}-meth-yl)-3-phenyl-prop-2-enoate.

Madhanraj R, Murugavel S, Kannan D, Bakthadoss M - Acta Crystallogr Sect E Struct Rep Online (2012)

A view of the C—H···π interactions, in the crystal structure of the title compound. Cg1 and Cg2 are the centroids of the (C18–C23) benzene and (C8–C13) benzene rings, respectively. [Symmetry code: (iii) x, 1+y, z; (iv) -x, 1-y, -z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3275177&req=5

Fap4: A view of the C—H···π interactions, in the crystal structure of the title compound. Cg1 and Cg2 are the centroids of the (C18–C23) benzene and (C8–C13) benzene rings, respectively. [Symmetry code: (iii) x, 1+y, z; (iv) -x, 1-y, -z.]
Bottom Line: In the title compound, C(25)H(25)NO(5)S, the O atom of the hy-droxy group is disordered over two positions, with occupancies of 0.820 (2) and 0.180 (2).The sulfonyl-bound benzene ring forms dihedral angles of 31.8 (1) and 60.7 (1)°, respectively, with the hy-droxy-methyl-benzene and phenyl rings.The crystal packing is stabilized by inter-molecular C-H⋯O hydrogen bonds and C-H⋯π inter-actions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(25)H(25)NO(5)S, the O atom of the hy-droxy group is disordered over two positions, with occupancies of 0.820 (2) and 0.180 (2). The sulfonyl-bound benzene ring forms dihedral angles of 31.8 (1) and 60.7 (1)°, respectively, with the hy-droxy-methyl-benzene and phenyl rings. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯O hydrogen bond, generating an S(8) ring motif. The crystal packing is stabilized by inter-molecular C-H⋯O hydrogen bonds and C-H⋯π inter-actions.

No MeSH data available.


Related in: MedlinePlus