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Improved conversion efficiency of Ag2S quantum dot-sensitized solar cells based on TiO2 nanotubes with a ZnO recombination barrier layer.

Chen C, Xie Y, Ali G, Yoo SH, Cho SO - Nanoscale Res Lett (2011)

Bottom Line: We improve the conversion efficiency of Ag2S quantum dot (QD)-sensitized TiO2 nanotube-array electrodes by chemically depositing ZnO recombination barrier layer on plain TiO2 nanotube-array electrodes.It is found that for the prepared electrodes, with increasing the cycles of Ag2S deposition, the photocurrent density and the conversion efficiency increase.In addition, as compared to the Ag2S QD-sensitized TiO2 nanotube-array electrode without the ZnO layers, the conversion efficiency of the electrode with the ZnO layers increases significantly due to the formation of efficient recombination layer between the TiO2 nanotube array and electrolyte.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Nuclear and Quantum Engineering, Korea Advanced Institute of Science and Technology (KAIST), 373-1 Guseong, Yuseong, Daejeon 305-701, Republic of Korea. socho@kaist.ac.kr.

ABSTRACT
We improve the conversion efficiency of Ag2S quantum dot (QD)-sensitized TiO2 nanotube-array electrodes by chemically depositing ZnO recombination barrier layer on plain TiO2 nanotube-array electrodes. The optical properties, structural properties, compositional analysis, and photoelectrochemistry properties of prepared electrodes have been investigated. It is found that for the prepared electrodes, with increasing the cycles of Ag2S deposition, the photocurrent density and the conversion efficiency increase. In addition, as compared to the Ag2S QD-sensitized TiO2 nanotube-array electrode without the ZnO layers, the conversion efficiency of the electrode with the ZnO layers increases significantly due to the formation of efficient recombination layer between the TiO2 nanotube array and electrolyte.

No MeSH data available.


SEM images of (a) the plain TNTs, (b) Ag2S(4)/TNTs, and (c) Ag2S(4)/ZnO/TNTs.
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Figure 2: SEM images of (a) the plain TNTs, (b) Ag2S(4)/TNTs, and (c) Ag2S(4)/ZnO/TNTs.

Mentions: Figure 2a shows the SEM image of the plain TNT film fabricated by anodization of Ti foil before coating with ZnO and Ag2S, which reveals a regularly arranged pore structure of the film. The average diameter of these pores is found to be approximately 200 nm and the thickness of the wall of the TNTs approximately 30 nm.


Improved conversion efficiency of Ag2S quantum dot-sensitized solar cells based on TiO2 nanotubes with a ZnO recombination barrier layer.

Chen C, Xie Y, Ali G, Yoo SH, Cho SO - Nanoscale Res Lett (2011)

SEM images of (a) the plain TNTs, (b) Ag2S(4)/TNTs, and (c) Ag2S(4)/ZnO/TNTs.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3211883&req=5

Figure 2: SEM images of (a) the plain TNTs, (b) Ag2S(4)/TNTs, and (c) Ag2S(4)/ZnO/TNTs.
Mentions: Figure 2a shows the SEM image of the plain TNT film fabricated by anodization of Ti foil before coating with ZnO and Ag2S, which reveals a regularly arranged pore structure of the film. The average diameter of these pores is found to be approximately 200 nm and the thickness of the wall of the TNTs approximately 30 nm.

Bottom Line: We improve the conversion efficiency of Ag2S quantum dot (QD)-sensitized TiO2 nanotube-array electrodes by chemically depositing ZnO recombination barrier layer on plain TiO2 nanotube-array electrodes.It is found that for the prepared electrodes, with increasing the cycles of Ag2S deposition, the photocurrent density and the conversion efficiency increase.In addition, as compared to the Ag2S QD-sensitized TiO2 nanotube-array electrode without the ZnO layers, the conversion efficiency of the electrode with the ZnO layers increases significantly due to the formation of efficient recombination layer between the TiO2 nanotube array and electrolyte.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Nuclear and Quantum Engineering, Korea Advanced Institute of Science and Technology (KAIST), 373-1 Guseong, Yuseong, Daejeon 305-701, Republic of Korea. socho@kaist.ac.kr.

ABSTRACT
We improve the conversion efficiency of Ag2S quantum dot (QD)-sensitized TiO2 nanotube-array electrodes by chemically depositing ZnO recombination barrier layer on plain TiO2 nanotube-array electrodes. The optical properties, structural properties, compositional analysis, and photoelectrochemistry properties of prepared electrodes have been investigated. It is found that for the prepared electrodes, with increasing the cycles of Ag2S deposition, the photocurrent density and the conversion efficiency increase. In addition, as compared to the Ag2S QD-sensitized TiO2 nanotube-array electrode without the ZnO layers, the conversion efficiency of the electrode with the ZnO layers increases significantly due to the formation of efficient recombination layer between the TiO2 nanotube array and electrolyte.

No MeSH data available.