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Poly[(μ(3)-benzene-1,3,5-tricarboxyl-ato-κO:O:O)(μ(2)-2-methyl-imidazolato-κN:N')tris-(2-methyl-imidazole-κN)dizinc(II)].

Maniam P, Stock N - Acta Crystallogr Sect E Struct Rep Online (2011)

Bottom Line: Hydro-thermal reaction involving zinc nitrate hexa-hydrate, tris-odium benzene-1,3,5-tricarboxyl-ate (Na(3)BTC) and 2-methyl-imidazole (2-MeImH) yielded the title compound, [Zn(2)(C(9)H(3)O(6))(C(4)H(5)N(2))(C(4)H(6)N(2))(3)].This results in two different distorted tetra-hedra, viz.ZnN(3)O and ZnN(2)O(2).

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, Max-Eyth-Strasse 2, 24118 Kiel, Germany.

ABSTRACT
Hydro-thermal reaction involving zinc nitrate hexa-hydrate, tris-odium benzene-1,3,5-tricarboxyl-ate (Na(3)BTC) and 2-methyl-imidazole (2-MeImH) yielded the title compound, [Zn(2)(C(9)H(3)O(6))(C(4)H(5)N(2))(C(4)H(6)N(2))(3)]. In this mixed-ligand metal-organic compound, Zn(2+) ions are coordinated by N atoms from 2-MeImH mol-ecules and (2-MeIm)(-) ions, as well as by O atoms from (BTC)(3-) ions. This results in two different distorted tetra-hedra, viz. ZnN(3)O and ZnN(2)O(2). These tetra-hedra are inter-connected via (BTC)(3-) ions and N:N'-bridging (2-MeIm)(-) ions, thus forming a layered structure in the bc plane. Hydrogen bonds between the O atoms of carboxyl-ate ions and NH groups of 2-MeImH ligands link the layers into a three-dimensional structure.

No MeSH data available.


Layer packing diagram of compound (I). All atoms of one layer are presented by the same colour. H-bonds (see Fig. 2) between the layers are depicted by black broken lines.
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Fap4: Layer packing diagram of compound (I). All atoms of one layer are presented by the same colour. H-bonds (see Fig. 2) between the layers are depicted by black broken lines.


Poly[(μ(3)-benzene-1,3,5-tricarboxyl-ato-κO:O:O)(μ(2)-2-methyl-imidazolato-κN:N')tris-(2-methyl-imidazole-κN)dizinc(II)].

Maniam P, Stock N - Acta Crystallogr Sect E Struct Rep Online (2011)

Layer packing diagram of compound (I). All atoms of one layer are presented by the same colour. H-bonds (see Fig. 2) between the layers are depicted by black broken lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3120569&req=5

Fap4: Layer packing diagram of compound (I). All atoms of one layer are presented by the same colour. H-bonds (see Fig. 2) between the layers are depicted by black broken lines.
Bottom Line: Hydro-thermal reaction involving zinc nitrate hexa-hydrate, tris-odium benzene-1,3,5-tricarboxyl-ate (Na(3)BTC) and 2-methyl-imidazole (2-MeImH) yielded the title compound, [Zn(2)(C(9)H(3)O(6))(C(4)H(5)N(2))(C(4)H(6)N(2))(3)].This results in two different distorted tetra-hedra, viz.ZnN(3)O and ZnN(2)O(2).

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, Max-Eyth-Strasse 2, 24118 Kiel, Germany.

ABSTRACT
Hydro-thermal reaction involving zinc nitrate hexa-hydrate, tris-odium benzene-1,3,5-tricarboxyl-ate (Na(3)BTC) and 2-methyl-imidazole (2-MeImH) yielded the title compound, [Zn(2)(C(9)H(3)O(6))(C(4)H(5)N(2))(C(4)H(6)N(2))(3)]. In this mixed-ligand metal-organic compound, Zn(2+) ions are coordinated by N atoms from 2-MeImH mol-ecules and (2-MeIm)(-) ions, as well as by O atoms from (BTC)(3-) ions. This results in two different distorted tetra-hedra, viz. ZnN(3)O and ZnN(2)O(2). These tetra-hedra are inter-connected via (BTC)(3-) ions and N:N'-bridging (2-MeIm)(-) ions, thus forming a layered structure in the bc plane. Hydrogen bonds between the O atoms of carboxyl-ate ions and NH groups of 2-MeImH ligands link the layers into a three-dimensional structure.

No MeSH data available.