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Poly[μ(3)-chlorido-μ(2)-chloridodichlorido(μ-dimethyl sulfoxide-κO:S)(dimethyl sulfoxide-κO)(μ-pyrimidine-κN:N')-ruthenium(III)sodium].

Ferrara S, Kreider-Mueller A, Tanski JM, Anderson CM - Acta Crystallogr Sect E Struct Rep Online (2011)

Bottom Line: The title complex, [NaRuCl(4)(C(4)H(4)N(2))(C(2)H(6)OS)(2)](n), is the sodium salt of monoanionic octa-hedral [Ru(III)Cl(4)(pyrimidine)(DMSO)](-) in which the sulfur-bound dimethyl sulfoxide (DMSO) and pyrimidine ligand are oriented trans to one another on the Ru(III) atom.The average of the four Ru-Cl bond lengths is 2.355 (15) Å, and the Ru-S and Ru-N bond lengths are 2.2853 (3) and 2.1165 (11) Å, respectively.The complex forms a chain, with a six-coordinate sodium ion bridging the ruthenium(III) units.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title complex, [NaRuCl(4)(C(4)H(4)N(2))(C(2)H(6)OS)(2)](n), is the sodium salt of monoanionic octa-hedral [Ru(III)Cl(4)(pyrimidine)(DMSO)](-) in which the sulfur-bound dimethyl sulfoxide (DMSO) and pyrimidine ligand are oriented trans to one another on the Ru(III) atom. The average of the four Ru-Cl bond lengths is 2.355 (15) Å, and the Ru-S and Ru-N bond lengths are 2.2853 (3) and 2.1165 (11) Å, respectively. The complex forms a chain, with a six-coordinate sodium ion bridging the ruthenium(III) units. The sodium cation is coordinated by cis-chloride ligands on ruthenium [Na-Cl = 2.9576 (7) and 2.6988 (7) Å], chloride and DMSO ligands from the ruthenium complexes related by inversion [Na-Cl and Na-O = 2.8888 (7) and 2.2623 (12) Å, respectively], a nitro-gen ligand from the pyrimidine of the tetrachlorido-ruthenium(III) complex related by the twofold rotation axis [Na-N = 2.5224 (14) Å] and an oxygen-bound DMSO [Na-O = 2.3165 (12) Å].

No MeSH data available.


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A view of the one-dimensional chain with displacement ellipsoids shown at the 50% probability level. Hydrogen atoms have been removed for clarity. [Symmetry codes: (i) -x + 1, -y, -z + 1; (ii) -x + 1, y, -z + 1/2; (iii) x, -y, z + 1/2].
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Fap2: A view of the one-dimensional chain with displacement ellipsoids shown at the 50% probability level. Hydrogen atoms have been removed for clarity. [Symmetry codes: (i) -x + 1, -y, -z + 1; (ii) -x + 1, y, -z + 1/2; (iii) x, -y, z + 1/2].


Poly[μ(3)-chlorido-μ(2)-chloridodichlorido(μ-dimethyl sulfoxide-κO:S)(dimethyl sulfoxide-κO)(μ-pyrimidine-κN:N')-ruthenium(III)sodium].

Ferrara S, Kreider-Mueller A, Tanski JM, Anderson CM - Acta Crystallogr Sect E Struct Rep Online (2011)

A view of the one-dimensional chain with displacement ellipsoids shown at the 50% probability level. Hydrogen atoms have been removed for clarity. [Symmetry codes: (i) -x + 1, -y, -z + 1; (ii) -x + 1, y, -z + 1/2; (iii) x, -y, z + 1/2].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3120471&req=5

Fap2: A view of the one-dimensional chain with displacement ellipsoids shown at the 50% probability level. Hydrogen atoms have been removed for clarity. [Symmetry codes: (i) -x + 1, -y, -z + 1; (ii) -x + 1, y, -z + 1/2; (iii) x, -y, z + 1/2].
Bottom Line: The title complex, [NaRuCl(4)(C(4)H(4)N(2))(C(2)H(6)OS)(2)](n), is the sodium salt of monoanionic octa-hedral [Ru(III)Cl(4)(pyrimidine)(DMSO)](-) in which the sulfur-bound dimethyl sulfoxide (DMSO) and pyrimidine ligand are oriented trans to one another on the Ru(III) atom.The average of the four Ru-Cl bond lengths is 2.355 (15) Å, and the Ru-S and Ru-N bond lengths are 2.2853 (3) and 2.1165 (11) Å, respectively.The complex forms a chain, with a six-coordinate sodium ion bridging the ruthenium(III) units.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title complex, [NaRuCl(4)(C(4)H(4)N(2))(C(2)H(6)OS)(2)](n), is the sodium salt of monoanionic octa-hedral [Ru(III)Cl(4)(pyrimidine)(DMSO)](-) in which the sulfur-bound dimethyl sulfoxide (DMSO) and pyrimidine ligand are oriented trans to one another on the Ru(III) atom. The average of the four Ru-Cl bond lengths is 2.355 (15) Å, and the Ru-S and Ru-N bond lengths are 2.2853 (3) and 2.1165 (11) Å, respectively. The complex forms a chain, with a six-coordinate sodium ion bridging the ruthenium(III) units. The sodium cation is coordinated by cis-chloride ligands on ruthenium [Na-Cl = 2.9576 (7) and 2.6988 (7) Å], chloride and DMSO ligands from the ruthenium complexes related by inversion [Na-Cl and Na-O = 2.8888 (7) and 2.2623 (12) Å, respectively], a nitro-gen ligand from the pyrimidine of the tetrachlorido-ruthenium(III) complex related by the twofold rotation axis [Na-N = 2.5224 (14) Å] and an oxygen-bound DMSO [Na-O = 2.3165 (12) Å].

No MeSH data available.


Related in: MedlinePlus