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(Dimethyl sulfoxide-κO)(2-formyl-phenolato-κO,O')[2-(2-oxidobenzyl-idene-amino)-phenolato-κO,N,O']manganese(III).

Raja I, Lo KM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2011)

Bottom Line: The O-C(6)H(4)-CH=N-C(6)H(4)-O dianion of the title compound, [Mn(C(13)H(9)NO(2))(C(7)H(5)O(2))(C(2)H(6)OS)], acts as an O,N,O'-chelate to bind to the Mn(III) atom, and the three atoms constitute three points [O-Mn-O = 174.43 (11)°] of an octa-hedron around the metal atom.The azomethine linkage is disordered over two positions in a 0.657 (13):0.343 (13) ratio.The deprotonated salicyldehyde anion acts as an O,O'-chelate; the sixth coordination site is represented by the O atom of the dimethyl sulfoxide mol-ecule.

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Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
The O-C(6)H(4)-CH=N-C(6)H(4)-O dianion of the title compound, [Mn(C(13)H(9)NO(2))(C(7)H(5)O(2))(C(2)H(6)OS)], acts as an O,N,O'-chelate to bind to the Mn(III) atom, and the three atoms constitute three points [O-Mn-O = 174.43 (11)°] of an octa-hedron around the metal atom. The azomethine linkage is disordered over two positions in a 0.657 (13):0.343 (13) ratio. The deprotonated salicyldehyde anion acts as an O,O'-chelate; the sixth coordination site is represented by the O atom of the dimethyl sulfoxide mol-ecule. The crystal studied was a non-merohedral twin with a minor twin component of 14.2 (3)%.

No MeSH data available.


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Thermal ellipsoid plot (Barbour, 2001) of Mn(C13H9NO2)(C7H5O3)(C2H6OS) at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius. The disordered azomethine linkage is shown in two conformations.
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Fap1: Thermal ellipsoid plot (Barbour, 2001) of Mn(C13H9NO2)(C7H5O3)(C2H6OS) at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius. The disordered azomethine linkage is shown in two conformations.


(Dimethyl sulfoxide-κO)(2-formyl-phenolato-κO,O')[2-(2-oxidobenzyl-idene-amino)-phenolato-κO,N,O']manganese(III).

Raja I, Lo KM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2011)

Thermal ellipsoid plot (Barbour, 2001) of Mn(C13H9NO2)(C7H5O3)(C2H6OS) at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius. The disordered azomethine linkage is shown in two conformations.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3120452&req=5

Fap1: Thermal ellipsoid plot (Barbour, 2001) of Mn(C13H9NO2)(C7H5O3)(C2H6OS) at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius. The disordered azomethine linkage is shown in two conformations.
Bottom Line: The O-C(6)H(4)-CH=N-C(6)H(4)-O dianion of the title compound, [Mn(C(13)H(9)NO(2))(C(7)H(5)O(2))(C(2)H(6)OS)], acts as an O,N,O'-chelate to bind to the Mn(III) atom, and the three atoms constitute three points [O-Mn-O = 174.43 (11)°] of an octa-hedron around the metal atom.The azomethine linkage is disordered over two positions in a 0.657 (13):0.343 (13) ratio.The deprotonated salicyldehyde anion acts as an O,O'-chelate; the sixth coordination site is represented by the O atom of the dimethyl sulfoxide mol-ecule.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
The O-C(6)H(4)-CH=N-C(6)H(4)-O dianion of the title compound, [Mn(C(13)H(9)NO(2))(C(7)H(5)O(2))(C(2)H(6)OS)], acts as an O,N,O'-chelate to bind to the Mn(III) atom, and the three atoms constitute three points [O-Mn-O = 174.43 (11)°] of an octa-hedron around the metal atom. The azomethine linkage is disordered over two positions in a 0.657 (13):0.343 (13) ratio. The deprotonated salicyldehyde anion acts as an O,O'-chelate; the sixth coordination site is represented by the O atom of the dimethyl sulfoxide mol-ecule. The crystal studied was a non-merohedral twin with a minor twin component of 14.2 (3)%.

No MeSH data available.


Related in: MedlinePlus