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Poly[di-μ(2)-chlorido-tri-μ(2)-terephthalato-tetra-lead(II)].

Yang L, Li Z, Li G - Acta Crystallogr Sect E Struct Rep Online (2011)

Bottom Line: The two Pb(2+) cations are each surrounded by five O atoms and one Cl atom in the form of irregular polyhedra.The cations are linked by μ(2)-O and μ(2)-Cl atoms into binuclear units, which are further extended through Pb-O inter-actions into an undulated inorganic layer parallel to (001).These layers are connected along [001] by the terephthalate groups into a three-dimensional framework.

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ABSTRACT
The title compound, [Pb(4)(C(8)H(4)O(4))(3)Cl(2)](n), consists of a three-dimensional inorganic-organic hybrid framework. The asymmetric unit contains two Pb(2+) cations, one Cl(-) anion and one and a half terephthalate anions, the latter being completed by inversion symmetry. The two Pb(2+) cations are each surrounded by five O atoms and one Cl atom in the form of irregular polyhedra. The cations are linked by μ(2)-O and μ(2)-Cl atoms into binuclear units, which are further extended through Pb-O inter-actions into an undulated inorganic layer parallel to (001). These layers are connected along [001] by the terephthalate groups into a three-dimensional framework.

No MeSH data available.


Related in: MedlinePlus

View of the structure along [100], showing the connection of the inorganic layers by terephthalic groups along [001].
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License
getmorefigures.php?uid=PMC3120444&req=5

Fap3: View of the structure along [100], showing the connection of the inorganic layers by terephthalic groups along [001].


Poly[di-μ(2)-chlorido-tri-μ(2)-terephthalato-tetra-lead(II)].

Yang L, Li Z, Li G - Acta Crystallogr Sect E Struct Rep Online (2011)

View of the structure along [100], showing the connection of the inorganic layers by terephthalic groups along [001].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3120444&req=5

Fap3: View of the structure along [100], showing the connection of the inorganic layers by terephthalic groups along [001].
Bottom Line: The two Pb(2+) cations are each surrounded by five O atoms and one Cl atom in the form of irregular polyhedra.The cations are linked by μ(2)-O and μ(2)-Cl atoms into binuclear units, which are further extended through Pb-O inter-actions into an undulated inorganic layer parallel to (001).These layers are connected along [001] by the terephthalate groups into a three-dimensional framework.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, [Pb(4)(C(8)H(4)O(4))(3)Cl(2)](n), consists of a three-dimensional inorganic-organic hybrid framework. The asymmetric unit contains two Pb(2+) cations, one Cl(-) anion and one and a half terephthalate anions, the latter being completed by inversion symmetry. The two Pb(2+) cations are each surrounded by five O atoms and one Cl atom in the form of irregular polyhedra. The cations are linked by μ(2)-O and μ(2)-Cl atoms into binuclear units, which are further extended through Pb-O inter-actions into an undulated inorganic layer parallel to (001). These layers are connected along [001] by the terephthalate groups into a three-dimensional framework.

No MeSH data available.


Related in: MedlinePlus