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Dichlorido(3-phenyl-indenyl-idene)bis-(triphenyl-phosphane)ruthenium(II) tetra-hydro-furan disolvate.

Bats JW, Pérez Gomes J, Doppiu A, Hashmi AS - Acta Crystallogr Sect E Struct Rep Online (2011)

Bottom Line: Acta Cryst.D65, 148-155].The molecular conformation shows three intramolecular C-H⋯Cl contacts and two C-H⋯π interactions while the crystal packing features an intermolecular C-H⋯Cl contact and two very weak intermolecular C-H⋯π contacts.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The Ru(II) atom in the title compound, [RuCl(2)(C(15)H(10))(C(18)H(15)P)(2)]·2C(4)H(8)O, has a distorted square-pyramidal conformation. The P and Cl atoms are at the base of the pyramid and the Ru-C(indenyl-idene) bond is in the axial position. The two Cl ligands and the two phosphane ligands are in trans positions. The Cl-Ru-Cl and P-Ru-P angles are 157.71 (2) and 166.83 (2)°, respectively. The two independent tetra-hydro-furan (THF) solvent mol-ecules are disordered. One THF mol-ecule was refined using a split-atom model. The second THF mol-ecule was accounted for by using program PLATON/SQUEEZE [Spek (2009 ▶). Acta Cryst. D65, 148-155]. The molecular conformation shows three intramolecular C-H⋯Cl contacts and two C-H⋯π interactions while the crystal packing features an intermolecular C-H⋯Cl contact and two very weak intermolecular C-H⋯π contacts.

No MeSH data available.


Related in: MedlinePlus

The structure of the title molecule shown with 50% probability displacement ellipsoids. The H atoms are drawn as small spheres of arbitrary radius. The disordered THF solvate molecule has been omitted.
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Fap1: The structure of the title molecule shown with 50% probability displacement ellipsoids. The H atoms are drawn as small spheres of arbitrary radius. The disordered THF solvate molecule has been omitted.


Dichlorido(3-phenyl-indenyl-idene)bis-(triphenyl-phosphane)ruthenium(II) tetra-hydro-furan disolvate.

Bats JW, Pérez Gomes J, Doppiu A, Hashmi AS - Acta Crystallogr Sect E Struct Rep Online (2011)

The structure of the title molecule shown with 50% probability displacement ellipsoids. The H atoms are drawn as small spheres of arbitrary radius. The disordered THF solvate molecule has been omitted.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3120390&req=5

Fap1: The structure of the title molecule shown with 50% probability displacement ellipsoids. The H atoms are drawn as small spheres of arbitrary radius. The disordered THF solvate molecule has been omitted.
Bottom Line: Acta Cryst.D65, 148-155].The molecular conformation shows three intramolecular C-H⋯Cl contacts and two C-H⋯π interactions while the crystal packing features an intermolecular C-H⋯Cl contact and two very weak intermolecular C-H⋯π contacts.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The Ru(II) atom in the title compound, [RuCl(2)(C(15)H(10))(C(18)H(15)P)(2)]·2C(4)H(8)O, has a distorted square-pyramidal conformation. The P and Cl atoms are at the base of the pyramid and the Ru-C(indenyl-idene) bond is in the axial position. The two Cl ligands and the two phosphane ligands are in trans positions. The Cl-Ru-Cl and P-Ru-P angles are 157.71 (2) and 166.83 (2)°, respectively. The two independent tetra-hydro-furan (THF) solvent mol-ecules are disordered. One THF mol-ecule was refined using a split-atom model. The second THF mol-ecule was accounted for by using program PLATON/SQUEEZE [Spek (2009 ▶). Acta Cryst. D65, 148-155]. The molecular conformation shows three intramolecular C-H⋯Cl contacts and two C-H⋯π interactions while the crystal packing features an intermolecular C-H⋯Cl contact and two very weak intermolecular C-H⋯π contacts.

No MeSH data available.


Related in: MedlinePlus