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Bis{μ-2-[(pyridin-2-yl)imino-meth-yl]phenolato}bis-[(2-formyl-phenolato)copper(II)].

Chang HC, Cole JM, Lin TC, Sylvester SO, Waddell PG - Acta Crystallogr Sect E Struct Rep Online (2011)

Bottom Line: The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)N(2)O)(2)(C(7)H(5)O(2))(2)], contains two independent (2-formyl-phen-olato){2-[(pyridin-2-yl)imino-meth-yl]phenolato}copper(II) mol-ecules that form pseudocentrosymmetric dimers via inter-actions between the Cu and pyridyl N atoms of independent monomers.The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer.The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17).

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Affiliation: Cavendish Laboratory, University of Cambridge, J. J. Thomson Avenue, Cambridge CB3 0HE, England.

ABSTRACT
The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)N(2)O)(2)(C(7)H(5)O(2))(2)], contains two independent (2-formyl-phen-olato){2-[(pyridin-2-yl)imino-meth-yl]phenolato}copper(II) mol-ecules that form pseudocentrosymmetric dimers via inter-actions between the Cu and pyridyl N atoms of independent monomers. The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer. The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17).

No MeSH data available.


The structure of the asymmetric unit of the title compound with displacement ellipsoids drawn at the 50% probability level.
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Fap1: The structure of the asymmetric unit of the title compound with displacement ellipsoids drawn at the 50% probability level.


Bis{μ-2-[(pyridin-2-yl)imino-meth-yl]phenolato}bis-[(2-formyl-phenolato)copper(II)].

Chang HC, Cole JM, Lin TC, Sylvester SO, Waddell PG - Acta Crystallogr Sect E Struct Rep Online (2011)

The structure of the asymmetric unit of the title compound with displacement ellipsoids drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3120375&req=5

Fap1: The structure of the asymmetric unit of the title compound with displacement ellipsoids drawn at the 50% probability level.
Bottom Line: The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)N(2)O)(2)(C(7)H(5)O(2))(2)], contains two independent (2-formyl-phen-olato){2-[(pyridin-2-yl)imino-meth-yl]phenolato}copper(II) mol-ecules that form pseudocentrosymmetric dimers via inter-actions between the Cu and pyridyl N atoms of independent monomers.The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer.The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17).

View Article: PubMed Central - HTML - PubMed

Affiliation: Cavendish Laboratory, University of Cambridge, J. J. Thomson Avenue, Cambridge CB3 0HE, England.

ABSTRACT
The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)N(2)O)(2)(C(7)H(5)O(2))(2)], contains two independent (2-formyl-phen-olato){2-[(pyridin-2-yl)imino-meth-yl]phenolato}copper(II) mol-ecules that form pseudocentrosymmetric dimers via inter-actions between the Cu and pyridyl N atoms of independent monomers. The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer. The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17).

No MeSH data available.