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Bis{μ-2-[(pyridin-2-yl)imino-meth-yl]phenolato}bis-[(2-formyl-phenolato)copper(II)].

Chang HC, Cole JM, Lin TC, Sylvester SO, Waddell PG - Acta Crystallogr Sect E Struct Rep Online (2011)

Bottom Line: The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)N(2)O)(2)(C(7)H(5)O(2))(2)], contains two independent (2-formyl-phen-olato){2-[(pyridin-2-yl)imino-meth-yl]phenolato}copper(II) mol-ecules that form pseudocentrosymmetric dimers via inter-actions between the Cu and pyridyl N atoms of independent monomers.The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer.The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17).

View Article: PubMed Central - HTML - PubMed

Affiliation: Cavendish Laboratory, University of Cambridge, J. J. Thomson Avenue, Cambridge CB3 0HE, England.

ABSTRACT
The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)N(2)O)(2)(C(7)H(5)O(2))(2)], contains two independent (2-formyl-phen-olato){2-[(pyridin-2-yl)imino-meth-yl]phenolato}copper(II) mol-ecules that form pseudocentrosymmetric dimers via inter-actions between the Cu and pyridyl N atoms of independent monomers. The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer. The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17).

No MeSH data available.


Related in: MedlinePlus

The structure of the asymmetric unit of the title compound with displacement ellipsoids drawn at the 50% probability level.
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Fap1: The structure of the asymmetric unit of the title compound with displacement ellipsoids drawn at the 50% probability level.


Bis{μ-2-[(pyridin-2-yl)imino-meth-yl]phenolato}bis-[(2-formyl-phenolato)copper(II)].

Chang HC, Cole JM, Lin TC, Sylvester SO, Waddell PG - Acta Crystallogr Sect E Struct Rep Online (2011)

The structure of the asymmetric unit of the title compound with displacement ellipsoids drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3120375&req=5

Fap1: The structure of the asymmetric unit of the title compound with displacement ellipsoids drawn at the 50% probability level.
Bottom Line: The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)N(2)O)(2)(C(7)H(5)O(2))(2)], contains two independent (2-formyl-phen-olato){2-[(pyridin-2-yl)imino-meth-yl]phenolato}copper(II) mol-ecules that form pseudocentrosymmetric dimers via inter-actions between the Cu and pyridyl N atoms of independent monomers.The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer.The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17).

View Article: PubMed Central - HTML - PubMed

Affiliation: Cavendish Laboratory, University of Cambridge, J. J. Thomson Avenue, Cambridge CB3 0HE, England.

ABSTRACT
The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)N(2)O)(2)(C(7)H(5)O(2))(2)], contains two independent (2-formyl-phen-olato){2-[(pyridin-2-yl)imino-meth-yl]phenolato}copper(II) mol-ecules that form pseudocentrosymmetric dimers via inter-actions between the Cu and pyridyl N atoms of independent monomers. The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer. The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17).

No MeSH data available.


Related in: MedlinePlus