Limits...
N,N,N',N'-Tetra-kis(2-hy-droxy-5-methyl-benz-yl)ethane-1,2-diamine dimethyl-formamide disolvate.

Wang NS, Wang YT, Guo XK, Li TD - Acta Crystallogr Sect E Struct Rep Online (2011)

Bottom Line: The mol-ecule and the dimethyl-formamide solvate are linked through an O-H⋯O hydrogen bond.An intra-molecular O-H⋯N hydrogen bond occurs in the tetra-phenol mol-ecule, which may influence the mol-ecular confomation.Futhermore, C-H⋯O and π-π stacking inter-actions [centroid-centroid distance = 3.7081 (14) Å] stabilize the crystal packing, building a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(34)H(40)N(2)O(4)·2C(3)H(7)NO, was synthesized by the Mannich condensation of ethane-diamine, formaldehyde and p-cresol. In the crystal, the tetra-phenol mol-ecule is arranged around an inversion center. The mol-ecule and the dimethyl-formamide solvate are linked through an O-H⋯O hydrogen bond. An intra-molecular O-H⋯N hydrogen bond occurs in the tetra-phenol mol-ecule, which may influence the mol-ecular confomation. Futhermore, C-H⋯O and π-π stacking inter-actions [centroid-centroid distance = 3.7081 (14) Å] stabilize the crystal packing, building a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus

Molecular structure of the title compound with the atom labeling scheme. Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small sphere of arbitrary radii. Hydrogen bonds are shown as dashed lines. Hydrogen atoms not involved in hydrogen bonding have been omitted for clarity. [Symmetry code: (i) -x+1, -y+1, -z+1]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3120359&req=5

Fap1: Molecular structure of the title compound with the atom labeling scheme. Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small sphere of arbitrary radii. Hydrogen bonds are shown as dashed lines. Hydrogen atoms not involved in hydrogen bonding have been omitted for clarity. [Symmetry code: (i) -x+1, -y+1, -z+1]


N,N,N',N'-Tetra-kis(2-hy-droxy-5-methyl-benz-yl)ethane-1,2-diamine dimethyl-formamide disolvate.

Wang NS, Wang YT, Guo XK, Li TD - Acta Crystallogr Sect E Struct Rep Online (2011)

Molecular structure of the title compound with the atom labeling scheme. Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small sphere of arbitrary radii. Hydrogen bonds are shown as dashed lines. Hydrogen atoms not involved in hydrogen bonding have been omitted for clarity. [Symmetry code: (i) -x+1, -y+1, -z+1]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3120359&req=5

Fap1: Molecular structure of the title compound with the atom labeling scheme. Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small sphere of arbitrary radii. Hydrogen bonds are shown as dashed lines. Hydrogen atoms not involved in hydrogen bonding have been omitted for clarity. [Symmetry code: (i) -x+1, -y+1, -z+1]
Bottom Line: The mol-ecule and the dimethyl-formamide solvate are linked through an O-H⋯O hydrogen bond.An intra-molecular O-H⋯N hydrogen bond occurs in the tetra-phenol mol-ecule, which may influence the mol-ecular confomation.Futhermore, C-H⋯O and π-π stacking inter-actions [centroid-centroid distance = 3.7081 (14) Å] stabilize the crystal packing, building a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(34)H(40)N(2)O(4)·2C(3)H(7)NO, was synthesized by the Mannich condensation of ethane-diamine, formaldehyde and p-cresol. In the crystal, the tetra-phenol mol-ecule is arranged around an inversion center. The mol-ecule and the dimethyl-formamide solvate are linked through an O-H⋯O hydrogen bond. An intra-molecular O-H⋯N hydrogen bond occurs in the tetra-phenol mol-ecule, which may influence the mol-ecular confomation. Futhermore, C-H⋯O and π-π stacking inter-actions [centroid-centroid distance = 3.7081 (14) Å] stabilize the crystal packing, building a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus