Limits...
Bis(dimethyl-ammonium) tetra-chlorido-dimethyl-stannate(IV).

Diop T, Diop L, Michaud F - Acta Crystallogr Sect E Struct Rep Online (2011)

Bottom Line: The Sn atom lies on a center of symmetry and is six-coordinated.It has a distorted octahedral SnC(2)Cl(4) environment with the Cl atoms in cis positions.The Cl atoms are connected to dimethyl-ammonium cations through N-H⋯Cl hydrogen bonds, forming an infinite chain extending parallel to [010].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
Regular crystals of the title compound, (C(2)H(8)N)(2)[Sn(CH(3))(2)Cl(4)], were obtained by reacting SnMe(2)Cl(2) with (CH(3))(2)NH·HCl in ethanol in a 1:1 ratio. The Sn atom lies on a center of symmetry and is six-coordinated. It has a distorted octahedral SnC(2)Cl(4) environment with the Cl atoms in cis positions. The Cl atoms are connected to dimethyl-ammonium cations through N-H⋯Cl hydrogen bonds, forming an infinite chain extending parallel to [010].

No MeSH data available.


Molecular packing around one anion implying hydrogen bonds (dashed lines) with the atom numbering used and 50% probability displacement elipsoids. Symmetry operations : ['] -x, -y, -z; [''] x, y+1,z, ['''] -x, -y, -z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3120357&req=5

Fap1: Molecular packing around one anion implying hydrogen bonds (dashed lines) with the atom numbering used and 50% probability displacement elipsoids. Symmetry operations : ['] -x, -y, -z; [''] x, y+1,z, ['''] -x, -y, -z.


Bis(dimethyl-ammonium) tetra-chlorido-dimethyl-stannate(IV).

Diop T, Diop L, Michaud F - Acta Crystallogr Sect E Struct Rep Online (2011)

Molecular packing around one anion implying hydrogen bonds (dashed lines) with the atom numbering used and 50% probability displacement elipsoids. Symmetry operations : ['] -x, -y, -z; [''] x, y+1,z, ['''] -x, -y, -z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3120357&req=5

Fap1: Molecular packing around one anion implying hydrogen bonds (dashed lines) with the atom numbering used and 50% probability displacement elipsoids. Symmetry operations : ['] -x, -y, -z; [''] x, y+1,z, ['''] -x, -y, -z.
Bottom Line: The Sn atom lies on a center of symmetry and is six-coordinated.It has a distorted octahedral SnC(2)Cl(4) environment with the Cl atoms in cis positions.The Cl atoms are connected to dimethyl-ammonium cations through N-H⋯Cl hydrogen bonds, forming an infinite chain extending parallel to [010].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
Regular crystals of the title compound, (C(2)H(8)N)(2)[Sn(CH(3))(2)Cl(4)], were obtained by reacting SnMe(2)Cl(2) with (CH(3))(2)NH·HCl in ethanol in a 1:1 ratio. The Sn atom lies on a center of symmetry and is six-coordinated. It has a distorted octahedral SnC(2)Cl(4) environment with the Cl atoms in cis positions. The Cl atoms are connected to dimethyl-ammonium cations through N-H⋯Cl hydrogen bonds, forming an infinite chain extending parallel to [010].

No MeSH data available.