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catena-Poly[[bis(pyridine)-lead(II)]bis(μ-penta-fluoro-benzene-thiol-ato)].

Appleton SE, Briand GG, Decken A, Smith AS - Acta Crystallogr Sect E Struct Rep Online (2011)

Bottom Line: The title compound, [Pb(C(6)F(5)S)(2)(C(5)H(5)N)(2)](n), shows the Pb(II) atom in a ψ-trigonal bipyramidal S(2)N(2) bonding environment.Pyridine N atoms occupy axial sites, while thiol-ate S atoms and a stereochemically active lone pair occupy equatorial sites.Very long inter-molecular Pb⋯S inter-actions [3.618 (4) and 3.614 (4) Å] yield a weakly associated one-dimensional polymeric structure extending parallel to [010].

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ABSTRACT
The title compound, [Pb(C(6)F(5)S)(2)(C(5)H(5)N)(2)](n), shows the Pb(II) atom in a ψ-trigonal bipyramidal S(2)N(2) bonding environment. Pyridine N atoms occupy axial sites, while thiol-ate S atoms and a stereochemically active lone pair occupy equatorial sites. Very long inter-molecular Pb⋯S inter-actions [3.618 (4) and 3.614 (4) Å] yield a weakly associated one-dimensional polymeric structure extending parallel to [010].

No MeSH data available.


Related in: MedlinePlus

X-ray crystal structure of (I) showing the polymeric structure, with displacement ellipsoids drawn at the 50% probability level. All hydrogen atoms and C6F5 group carbon atoms (except α-carbon) have been omitted for clarity. Symmetry transformations used to generate equivalent atoms: (i) -1 + x, y, z; (ii) +1 + x, y, z.
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Fap2: X-ray crystal structure of (I) showing the polymeric structure, with displacement ellipsoids drawn at the 50% probability level. All hydrogen atoms and C6F5 group carbon atoms (except α-carbon) have been omitted for clarity. Symmetry transformations used to generate equivalent atoms: (i) -1 + x, y, z; (ii) +1 + x, y, z.


catena-Poly[[bis(pyridine)-lead(II)]bis(μ-penta-fluoro-benzene-thiol-ato)].

Appleton SE, Briand GG, Decken A, Smith AS - Acta Crystallogr Sect E Struct Rep Online (2011)

X-ray crystal structure of (I) showing the polymeric structure, with displacement ellipsoids drawn at the 50% probability level. All hydrogen atoms and C6F5 group carbon atoms (except α-carbon) have been omitted for clarity. Symmetry transformations used to generate equivalent atoms: (i) -1 + x, y, z; (ii) +1 + x, y, z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3120355&req=5

Fap2: X-ray crystal structure of (I) showing the polymeric structure, with displacement ellipsoids drawn at the 50% probability level. All hydrogen atoms and C6F5 group carbon atoms (except α-carbon) have been omitted for clarity. Symmetry transformations used to generate equivalent atoms: (i) -1 + x, y, z; (ii) +1 + x, y, z.
Bottom Line: The title compound, [Pb(C(6)F(5)S)(2)(C(5)H(5)N)(2)](n), shows the Pb(II) atom in a ψ-trigonal bipyramidal S(2)N(2) bonding environment.Pyridine N atoms occupy axial sites, while thiol-ate S atoms and a stereochemically active lone pair occupy equatorial sites.Very long inter-molecular Pb⋯S inter-actions [3.618 (4) and 3.614 (4) Å] yield a weakly associated one-dimensional polymeric structure extending parallel to [010].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, [Pb(C(6)F(5)S)(2)(C(5)H(5)N)(2)](n), shows the Pb(II) atom in a ψ-trigonal bipyramidal S(2)N(2) bonding environment. Pyridine N atoms occupy axial sites, while thiol-ate S atoms and a stereochemically active lone pair occupy equatorial sites. Very long inter-molecular Pb⋯S inter-actions [3.618 (4) and 3.614 (4) Å] yield a weakly associated one-dimensional polymeric structure extending parallel to [010].

No MeSH data available.


Related in: MedlinePlus