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Chloridotetra-pyridine-copper(II) dicyanamidate pyridine disolvate.

Wöhlert S, Wriedt M, Jess I, Näther C - Acta Crystallogr Sect E Struct Rep Online (2011)

Bottom Line: However, there is one additional chloride anion at 3.0065 (9) Å, leading to a disorted octa-hedral coordination mode for copper.The copper(II) cation, the chloride ligand and the central N atom of the dicyanamide anion are located on twofold rotation axes.Two pyridine solvent molecules are observed in general positions.

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ABSTRACT
In the crystal structure of the title compound, [CuCl(C(5)H(5)N)(4)][N(CN)(2)]·2C(6)H(5)N, the copper(II) cations are coordinated by one chloride anion and four N-bonded pyridine ligands into discrete complexes. The copper(II) cation shows a square-pyramidal coordination environment, with the chloride anion in the apical position. However, there is one additional chloride anion at 3.0065 (9) Å, leading to a disorted octa-hedral coordination mode for copper. The copper(II) cation, the chloride ligand and the central N atom of the dicyanamide anion are located on twofold rotation axes. Two pyridine solvent molecules are observed in general positions.

No MeSH data available.


: Crystal structure of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level. Symmetry codes: i = -x+1, -y+1, z; ii = -x+2, -y+1, z.
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Fap1: : Crystal structure of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level. Symmetry codes: i = -x+1, -y+1, z; ii = -x+2, -y+1, z.


Chloridotetra-pyridine-copper(II) dicyanamidate pyridine disolvate.

Wöhlert S, Wriedt M, Jess I, Näther C - Acta Crystallogr Sect E Struct Rep Online (2011)

: Crystal structure of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level. Symmetry codes: i = -x+1, -y+1, z; ii = -x+2, -y+1, z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3120354&req=5

Fap1: : Crystal structure of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level. Symmetry codes: i = -x+1, -y+1, z; ii = -x+2, -y+1, z.
Bottom Line: However, there is one additional chloride anion at 3.0065 (9) Å, leading to a disorted octa-hedral coordination mode for copper.The copper(II) cation, the chloride ligand and the central N atom of the dicyanamide anion are located on twofold rotation axes.Two pyridine solvent molecules are observed in general positions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the crystal structure of the title compound, [CuCl(C(5)H(5)N)(4)][N(CN)(2)]·2C(6)H(5)N, the copper(II) cations are coordinated by one chloride anion and four N-bonded pyridine ligands into discrete complexes. The copper(II) cation shows a square-pyramidal coordination environment, with the chloride anion in the apical position. However, there is one additional chloride anion at 3.0065 (9) Å, leading to a disorted octa-hedral coordination mode for copper. The copper(II) cation, the chloride ligand and the central N atom of the dicyanamide anion are located on twofold rotation axes. Two pyridine solvent molecules are observed in general positions.

No MeSH data available.