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[N'-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihy-droxy-benzohydrazidato-κN',O](methanol-κO)dioxidomolybdenum(VI)-4,4'-bipyridine (1/1).

Ngan NK, Wong RC, Lo KM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2011)

Bottom Line: In the title co-crystal, [Mo(C(14)H(9)ClN(2)O(4))O(2)(CH(3)OH)]·C(10)H(8)N(2), the deprotonated Schiff base O,N,O'-chelates to the Mo(VI) atom, the three atoms involved in chelation comprising the fac sites of the octa-hedron surrounding the methanol-coordinated metal atom.The methanol mol-ecule forms an O-H⋯N hydrogen bond to an N atom of the 4,4'-bipyridine solvent mol-ecule; the hy-droxy group of the Schiff base forms an O-H⋯N hydrogen bond to the other N atom of another mol-ecule.The two hydrogen bonds leading to the formation of a helical chain running along the b axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
In the title co-crystal, [Mo(C(14)H(9)ClN(2)O(4))O(2)(CH(3)OH)]·C(10)H(8)N(2), the deprotonated Schiff base O,N,O'-chelates to the Mo(VI) atom, the three atoms involved in chelation comprising the fac sites of the octa-hedron surrounding the methanol-coordinated metal atom. The methanol mol-ecule forms an O-H⋯N hydrogen bond to an N atom of the 4,4'-bipyridine solvent mol-ecule; the hy-droxy group of the Schiff base forms an O-H⋯N hydrogen bond to the other N atom of another mol-ecule. The two hydrogen bonds leading to the formation of a helical chain running along the b axis.

No MeSH data available.


Related in: MedlinePlus

Thermal ellipsoid plot (Barbour, 2001) of MoO2(CH3OH)(C14H9ClN2O4).C10H8N2 at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
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Fap1: Thermal ellipsoid plot (Barbour, 2001) of MoO2(CH3OH)(C14H9ClN2O4).C10H8N2 at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.


[N'-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihy-droxy-benzohydrazidato-κN',O](methanol-κO)dioxidomolybdenum(VI)-4,4'-bipyridine (1/1).

Ngan NK, Wong RC, Lo KM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2011)

Thermal ellipsoid plot (Barbour, 2001) of MoO2(CH3OH)(C14H9ClN2O4).C10H8N2 at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3120353&req=5

Fap1: Thermal ellipsoid plot (Barbour, 2001) of MoO2(CH3OH)(C14H9ClN2O4).C10H8N2 at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
Bottom Line: In the title co-crystal, [Mo(C(14)H(9)ClN(2)O(4))O(2)(CH(3)OH)]·C(10)H(8)N(2), the deprotonated Schiff base O,N,O'-chelates to the Mo(VI) atom, the three atoms involved in chelation comprising the fac sites of the octa-hedron surrounding the methanol-coordinated metal atom.The methanol mol-ecule forms an O-H⋯N hydrogen bond to an N atom of the 4,4'-bipyridine solvent mol-ecule; the hy-droxy group of the Schiff base forms an O-H⋯N hydrogen bond to the other N atom of another mol-ecule.The two hydrogen bonds leading to the formation of a helical chain running along the b axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
In the title co-crystal, [Mo(C(14)H(9)ClN(2)O(4))O(2)(CH(3)OH)]·C(10)H(8)N(2), the deprotonated Schiff base O,N,O'-chelates to the Mo(VI) atom, the three atoms involved in chelation comprising the fac sites of the octa-hedron surrounding the methanol-coordinated metal atom. The methanol mol-ecule forms an O-H⋯N hydrogen bond to an N atom of the 4,4'-bipyridine solvent mol-ecule; the hy-droxy group of the Schiff base forms an O-H⋯N hydrogen bond to the other N atom of another mol-ecule. The two hydrogen bonds leading to the formation of a helical chain running along the b axis.

No MeSH data available.


Related in: MedlinePlus