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Tris(morpholinium) hexa-μ(3)-hydroxido-hexa-μ(2)-oxido-dodeca-oxidohexa-molybdenum(VI)chromate(III) tetra-hydrate.

Yang YY, Song Y, Liu LY, Qu XS - Acta Crystallogr Sect E Struct Rep Online (2011)

Bottom Line: In the title organic-inorganic hybrid compound, (C(4)H(10)NO)(3)[H(6)CrMo(6)O(24)]·4H(2)O, the Anderson-type [H(6)CrMo(6)O(24)](3-) polyoxoanion is centrosymmetric, with the Cr(III) ion lying on an inversion center.One of the two crystallographiclly independent morpholinium cations is half-occupied.Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the cations, polyoxoanions and uncoordinated water mol-ecules.

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ABSTRACT
In the title organic-inorganic hybrid compound, (C(4)H(10)NO)(3)[H(6)CrMo(6)O(24)]·4H(2)O, the Anderson-type [H(6)CrMo(6)O(24)](3-) polyoxoanion is centrosymmetric, with the Cr(III) ion lying on an inversion center. One of the two crystallographiclly independent morpholinium cations is half-occupied. Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the cations, polyoxoanions and uncoordinated water mol-ecules.

No MeSH data available.


Related in: MedlinePlus

The structure of the title compound, with displacement ellipsoids drawn at the 50% probability level. The morpholinium cation containing N2 is half-occupied. H atoms have been omitted for clarity. [Symmetry code: (i) -x, -y, -z.]
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Fap1: The structure of the title compound, with displacement ellipsoids drawn at the 50% probability level. The morpholinium cation containing N2 is half-occupied. H atoms have been omitted for clarity. [Symmetry code: (i) -x, -y, -z.]


Tris(morpholinium) hexa-μ(3)-hydroxido-hexa-μ(2)-oxido-dodeca-oxidohexa-molybdenum(VI)chromate(III) tetra-hydrate.

Yang YY, Song Y, Liu LY, Qu XS - Acta Crystallogr Sect E Struct Rep Online (2011)

The structure of the title compound, with displacement ellipsoids drawn at the 50% probability level. The morpholinium cation containing N2 is half-occupied. H atoms have been omitted for clarity. [Symmetry code: (i) -x, -y, -z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3120305&req=5

Fap1: The structure of the title compound, with displacement ellipsoids drawn at the 50% probability level. The morpholinium cation containing N2 is half-occupied. H atoms have been omitted for clarity. [Symmetry code: (i) -x, -y, -z.]
Bottom Line: In the title organic-inorganic hybrid compound, (C(4)H(10)NO)(3)[H(6)CrMo(6)O(24)]·4H(2)O, the Anderson-type [H(6)CrMo(6)O(24)](3-) polyoxoanion is centrosymmetric, with the Cr(III) ion lying on an inversion center.One of the two crystallographiclly independent morpholinium cations is half-occupied.Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the cations, polyoxoanions and uncoordinated water mol-ecules.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title organic-inorganic hybrid compound, (C(4)H(10)NO)(3)[H(6)CrMo(6)O(24)]·4H(2)O, the Anderson-type [H(6)CrMo(6)O(24)](3-) polyoxoanion is centrosymmetric, with the Cr(III) ion lying on an inversion center. One of the two crystallographiclly independent morpholinium cations is half-occupied. Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the cations, polyoxoanions and uncoordinated water mol-ecules.

No MeSH data available.


Related in: MedlinePlus