Limits...
[4'-(4-Amino-phen-yl)-2,2':6',2''-terpyridine]-chloridopalladium(II) chloride.

Thomas JC, Tiekink ER, Walmsley JA - Acta Crystallogr Sect E Struct Rep Online (2011)

Bottom Line: The Pd(II) atom in the complex cation of the title compound, [PdCl(C(21)H(16)N(4))]Cl, is coordinated by three N atoms derived from the terpyridine ligand and a chloride ion, which define a distorted PdClN(3) square-planar coordination geometry.In the crystal, the presence of N-H⋯Cl hydrogen bonds involving the amino H atom and chloride anions link two cations and two anions into a four-ion aggregate via centrosymmetric eight-membered [⋯H-N-H⋯Cl](2) synthons.Layers of cations are inter-spersed with the chloride anions with stabilization provided by C-H⋯Cl inter-actions involving both Cl atoms, as well as π-π inter-actions [the closest inter-action of 3.489 (6) Å occurs between a chelate ring and a pyridyl residue].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The Pd(II) atom in the complex cation of the title compound, [PdCl(C(21)H(16)N(4))]Cl, is coordinated by three N atoms derived from the terpyridine ligand and a chloride ion, which define a distorted PdClN(3) square-planar coordination geometry. In the crystal, the presence of N-H⋯Cl hydrogen bonds involving the amino H atom and chloride anions link two cations and two anions into a four-ion aggregate via centrosymmetric eight-membered [⋯H-N-H⋯Cl](2) synthons. Layers of cations are inter-spersed with the chloride anions with stabilization provided by C-H⋯Cl inter-actions involving both Cl atoms, as well as π-π inter-actions [the closest inter-action of 3.489 (6) Å occurs between a chelate ring and a pyridyl residue].

No MeSH data available.


Molecular structure of (I) showing displacement ellipsoids at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3120294&req=5

Fap1: Molecular structure of (I) showing displacement ellipsoids at the 50% probability level.


[4'-(4-Amino-phen-yl)-2,2':6',2''-terpyridine]-chloridopalladium(II) chloride.

Thomas JC, Tiekink ER, Walmsley JA - Acta Crystallogr Sect E Struct Rep Online (2011)

Molecular structure of (I) showing displacement ellipsoids at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3120294&req=5

Fap1: Molecular structure of (I) showing displacement ellipsoids at the 50% probability level.
Bottom Line: The Pd(II) atom in the complex cation of the title compound, [PdCl(C(21)H(16)N(4))]Cl, is coordinated by three N atoms derived from the terpyridine ligand and a chloride ion, which define a distorted PdClN(3) square-planar coordination geometry.In the crystal, the presence of N-H⋯Cl hydrogen bonds involving the amino H atom and chloride anions link two cations and two anions into a four-ion aggregate via centrosymmetric eight-membered [⋯H-N-H⋯Cl](2) synthons.Layers of cations are inter-spersed with the chloride anions with stabilization provided by C-H⋯Cl inter-actions involving both Cl atoms, as well as π-π inter-actions [the closest inter-action of 3.489 (6) Å occurs between a chelate ring and a pyridyl residue].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The Pd(II) atom in the complex cation of the title compound, [PdCl(C(21)H(16)N(4))]Cl, is coordinated by three N atoms derived from the terpyridine ligand and a chloride ion, which define a distorted PdClN(3) square-planar coordination geometry. In the crystal, the presence of N-H⋯Cl hydrogen bonds involving the amino H atom and chloride anions link two cations and two anions into a four-ion aggregate via centrosymmetric eight-membered [⋯H-N-H⋯Cl](2) synthons. Layers of cations are inter-spersed with the chloride anions with stabilization provided by C-H⋯Cl inter-actions involving both Cl atoms, as well as π-π inter-actions [the closest inter-action of 3.489 (6) Å occurs between a chelate ring and a pyridyl residue].

No MeSH data available.