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(2,2'-Bipyridine-κN,N')dichloridobis(4-fluoro-benz-yl)tin(IV).

Keng TC, Lo KM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2011)

Bottom Line: The six-coordinate Sn(IV) atom in the title compound, [Sn(C(7)H(6)F)(2)Cl(2)(C(10)H(8)N(2))], shows a trans-C(2)SnN(2)Cl(2) octa-hedral coordination [C-Sn-C = 174.81 (10) and 176.71 (9)° in the two independent mol-ecules in the asymmetric unit]; the Cl atoms are cis to each other as are the N atoms of the chelating N-heterocycle.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
The six-coordinate Sn(IV) atom in the title compound, [Sn(C(7)H(6)F)(2)Cl(2)(C(10)H(8)N(2))], shows a trans-C(2)SnN(2)Cl(2) octa-hedral coordination [C-Sn-C = 174.81 (10) and 176.71 (9)° in the two independent mol-ecules in the asymmetric unit]; the Cl atoms are cis to each other as are the N atoms of the chelating N-heterocycle.

No MeSH data available.


Anisotropic displacement ellipsoid plot (Barbour, 2001) of SnCl2(C10H8N2)(C7H6F)2 at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
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Fap1: Anisotropic displacement ellipsoid plot (Barbour, 2001) of SnCl2(C10H8N2)(C7H6F)2 at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.


(2,2'-Bipyridine-κN,N')dichloridobis(4-fluoro-benz-yl)tin(IV).

Keng TC, Lo KM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2011)

Anisotropic displacement ellipsoid plot (Barbour, 2001) of SnCl2(C10H8N2)(C7H6F)2 at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3120283&req=5

Fap1: Anisotropic displacement ellipsoid plot (Barbour, 2001) of SnCl2(C10H8N2)(C7H6F)2 at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
Bottom Line: The six-coordinate Sn(IV) atom in the title compound, [Sn(C(7)H(6)F)(2)Cl(2)(C(10)H(8)N(2))], shows a trans-C(2)SnN(2)Cl(2) octa-hedral coordination [C-Sn-C = 174.81 (10) and 176.71 (9)° in the two independent mol-ecules in the asymmetric unit]; the Cl atoms are cis to each other as are the N atoms of the chelating N-heterocycle.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
The six-coordinate Sn(IV) atom in the title compound, [Sn(C(7)H(6)F)(2)Cl(2)(C(10)H(8)N(2))], shows a trans-C(2)SnN(2)Cl(2) octa-hedral coordination [C-Sn-C = 174.81 (10) and 176.71 (9)° in the two independent mol-ecules in the asymmetric unit]; the Cl atoms are cis to each other as are the N atoms of the chelating N-heterocycle.

No MeSH data available.