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Tris(4-methyl-phen-yl)phosphine selenide.

Muller A - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: Dokl.Akad.USSR), 92, 983-985] contained no geometrical data.

View Article: PubMed Central - HTML - PubMed

Affiliation: Research Centre in Synthesis and Catalysis, Department of Chemistry, University of Johannesburg (APK Campus), PO Box 524, Auckland Park, Johannesburg 2006, South Africa.

ABSTRACT
In the title mol-ecule, C(21)H(21)PSe or PSe(C(7)H(7))(3), the P atom has a distorted PSeC(3) tetra-hedral environment, formed by the Se atom [P=Se = 2.1119 (5) Å] and three aryl rings. Two short intra-molecular C-H⋯Se contacts occur. In the crystal, weak inter-molecular C-H⋯Se inter-actions link the mol-ecules into zigzag double chains propagating in [100]. The previous report of this structure [Zhdanov et al. (1953 ▶). Dokl. Akad. Nauk SSSR (Russ.) (Proc. Nat. Acad. Sci. USSR), 92, 983-985] contained no geometrical data.

No MeSH data available.


Related in: MedlinePlus

View of (I) (50% probability displacement ellipsoids). H atoms have been omitted for clarity. For the C atoms, the first digit indicates the ring number and the second digit indicates the position of the atom in the ring.
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Fap1: View of (I) (50% probability displacement ellipsoids). H atoms have been omitted for clarity. For the C atoms, the first digit indicates the ring number and the second digit indicates the position of the atom in the ring.


Tris(4-methyl-phen-yl)phosphine selenide.

Muller A - Acta Crystallogr Sect E Struct Rep Online (2010)

View of (I) (50% probability displacement ellipsoids). H atoms have been omitted for clarity. For the C atoms, the first digit indicates the ring number and the second digit indicates the position of the atom in the ring.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050420&req=5

Fap1: View of (I) (50% probability displacement ellipsoids). H atoms have been omitted for clarity. For the C atoms, the first digit indicates the ring number and the second digit indicates the position of the atom in the ring.
Bottom Line: Dokl.Akad.USSR), 92, 983-985] contained no geometrical data.

View Article: PubMed Central - HTML - PubMed

Affiliation: Research Centre in Synthesis and Catalysis, Department of Chemistry, University of Johannesburg (APK Campus), PO Box 524, Auckland Park, Johannesburg 2006, South Africa.

ABSTRACT
In the title mol-ecule, C(21)H(21)PSe or PSe(C(7)H(7))(3), the P atom has a distorted PSeC(3) tetra-hedral environment, formed by the Se atom [P=Se = 2.1119 (5) Å] and three aryl rings. Two short intra-molecular C-H⋯Se contacts occur. In the crystal, weak inter-molecular C-H⋯Se inter-actions link the mol-ecules into zigzag double chains propagating in [100]. The previous report of this structure [Zhdanov et al. (1953 ▶). Dokl. Akad. Nauk SSSR (Russ.) (Proc. Nat. Acad. Sci. USSR), 92, 983-985] contained no geometrical data.

No MeSH data available.


Related in: MedlinePlus