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Dichlorido(η-p-cymene)(4-fluoro-aniline-κN)ruthenium(II).

Sykora RE, Harris AG, Clements JW, Hoffman NW - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The title compound, [RuCl(2)(C(10)H(14))(C(6)H(6)FN)], a pseudo-octa-hedral d(6) complex, has the expected piano-stool geometry around the Ru(II) atom.The fluoro-aniline ring forms a dihedral angle of 19.3 (2)° with the p-cymene ring.Weak inter-molecular C-H⋯Cl inter-actions involving the p-cymene ring consolidate the crystal packing.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of South Alabama, Mobile, AL 36688-0002, USA.

ABSTRACT
The title compound, [RuCl(2)(C(10)H(14))(C(6)H(6)FN)], a pseudo-octa-hedral d(6) complex, has the expected piano-stool geometry around the Ru(II) atom. The fluoro-aniline ring forms a dihedral angle of 19.3 (2)° with the p-cymene ring. In the crystal, two mol-ecules form an inversion dimer via a pair of N-H⋯Cl hydrogen bonds. Weak inter-molecular C-H⋯Cl inter-actions involving the p-cymene ring consolidate the crystal packing.

No MeSH data available.


Related in: MedlinePlus

19F NMR Spectrum of the Equilibrium Mixture Prepared by Mixing Equimolar Amounts of (η6-p-cymene)Ru(4—F—C6H4NH2)Cl2 and P(O-2,4-But2-C6H3)3 in CDCl3 at 23 °C.
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Fap3: 19F NMR Spectrum of the Equilibrium Mixture Prepared by Mixing Equimolar Amounts of (η6-p-cymene)Ru(4—F—C6H4NH2)Cl2 and P(O-2,4-But2-C6H3)3 in CDCl3 at 23 °C.


Dichlorido(η-p-cymene)(4-fluoro-aniline-κN)ruthenium(II).

Sykora RE, Harris AG, Clements JW, Hoffman NW - Acta Crystallogr Sect E Struct Rep Online (2010)

19F NMR Spectrum of the Equilibrium Mixture Prepared by Mixing Equimolar Amounts of (η6-p-cymene)Ru(4—F—C6H4NH2)Cl2 and P(O-2,4-But2-C6H3)3 in CDCl3 at 23 °C.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050405&req=5

Fap3: 19F NMR Spectrum of the Equilibrium Mixture Prepared by Mixing Equimolar Amounts of (η6-p-cymene)Ru(4—F—C6H4NH2)Cl2 and P(O-2,4-But2-C6H3)3 in CDCl3 at 23 °C.
Bottom Line: The title compound, [RuCl(2)(C(10)H(14))(C(6)H(6)FN)], a pseudo-octa-hedral d(6) complex, has the expected piano-stool geometry around the Ru(II) atom.The fluoro-aniline ring forms a dihedral angle of 19.3 (2)° with the p-cymene ring.Weak inter-molecular C-H⋯Cl inter-actions involving the p-cymene ring consolidate the crystal packing.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of South Alabama, Mobile, AL 36688-0002, USA.

ABSTRACT
The title compound, [RuCl(2)(C(10)H(14))(C(6)H(6)FN)], a pseudo-octa-hedral d(6) complex, has the expected piano-stool geometry around the Ru(II) atom. The fluoro-aniline ring forms a dihedral angle of 19.3 (2)° with the p-cymene ring. In the crystal, two mol-ecules form an inversion dimer via a pair of N-H⋯Cl hydrogen bonds. Weak inter-molecular C-H⋯Cl inter-actions involving the p-cymene ring consolidate the crystal packing.

No MeSH data available.


Related in: MedlinePlus