Limits...
[μ-Bis(diphenyl-phosphan-yl)acetonitrile-κP:P]bis-[chloridogold(I)].

Sithole SV, Staples RJ, van Zyl WE - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The Cl-Au-P bond angle of 176.84 (7)° is slightly distorted from linearity.The C-C N fragment is essentially linear at 179.5 (9)° and the C N bond length of 1.125 (11) Å indicates predominantly triple-bond character.In the crystal packing, there are no hydrogen-bonding or aurophilic inter-actions between the mol-ecules.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title complex, [Au(2)Cl(2)(C(26)H(21)NP(2))], has an intra-molecular Au⋯Au inter-action of 3.1669 (4) Å, but no inter-molecular Au⋯Au inter-actions in the solid state. The Cl-Au-P bond angle of 176.84 (7)° is slightly distorted from linearity. The P-C bond length to the phenyl group is shorter [1.810 (7) Å] than the P-C bond length [1.876 (7) Å] to the bridging carbon, indicative of the flexibility of the bidentate bite of the ligand. The C-C N fragment is essentially linear at 179.5 (9)° and the C N bond length of 1.125 (11) Å indicates predominantly triple-bond character. In the crystal packing, there are no hydrogen-bonding or aurophilic inter-actions between the mol-ecules.

No MeSH data available.


Related in: MedlinePlus

Molecular structure of the title complex showing the atom numbering scheme. Ellipsoids are drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3050401&req=5

Fap1: Molecular structure of the title complex showing the atom numbering scheme. Ellipsoids are drawn at the 50% probability level.


[μ-Bis(diphenyl-phosphan-yl)acetonitrile-κP:P]bis-[chloridogold(I)].

Sithole SV, Staples RJ, van Zyl WE - Acta Crystallogr Sect E Struct Rep Online (2010)

Molecular structure of the title complex showing the atom numbering scheme. Ellipsoids are drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050401&req=5

Fap1: Molecular structure of the title complex showing the atom numbering scheme. Ellipsoids are drawn at the 50% probability level.
Bottom Line: The Cl-Au-P bond angle of 176.84 (7)° is slightly distorted from linearity.The C-C N fragment is essentially linear at 179.5 (9)° and the C N bond length of 1.125 (11) Å indicates predominantly triple-bond character.In the crystal packing, there are no hydrogen-bonding or aurophilic inter-actions between the mol-ecules.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title complex, [Au(2)Cl(2)(C(26)H(21)NP(2))], has an intra-molecular Au⋯Au inter-action of 3.1669 (4) Å, but no inter-molecular Au⋯Au inter-actions in the solid state. The Cl-Au-P bond angle of 176.84 (7)° is slightly distorted from linearity. The P-C bond length to the phenyl group is shorter [1.810 (7) Å] than the P-C bond length [1.876 (7) Å] to the bridging carbon, indicative of the flexibility of the bidentate bite of the ligand. The C-C N fragment is essentially linear at 179.5 (9)° and the C N bond length of 1.125 (11) Å indicates predominantly triple-bond character. In the crystal packing, there are no hydrogen-bonding or aurophilic inter-actions between the mol-ecules.

No MeSH data available.


Related in: MedlinePlus