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(RS)-1-[5-(2-Chloro-prop-yl)indolin-1-yl]ethanone.

Yang XM - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: Indeed, the Cl and CH(3) groups located on the stereogenic carbon exchange with each other.The whole crystal is a racemate.Non-classical C-H⋯O hydrogen bonds between symmetry-related benzene rings stabilize the crystal structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Guangdong Medical College, Dongguan 523808, People's Republic of China.

ABSTRACT
In the title compound, C(13)H(16)ClNO, the acetyl-indoline moiety is roughly planar (r.m.s. deviation = 0.0048 Å). The chloro-propyl group is out of the plane and is statistically disordered over two positions. Indeed, the Cl and CH(3) groups located on the stereogenic carbon exchange with each other. The whole crystal is a racemate. Non-classical C-H⋯O hydrogen bonds between symmetry-related benzene rings stabilize the crystal structure.

No MeSH data available.


Partial packing view of compound ( I ), showing the formation of chains along [010] built from hydrogen bonds represented as dashed lines. H atoms not involved in hydrogen bonding have been omitted for clarity. [Symmetry code: (i) x, y-1, z]
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Fap2: Partial packing view of compound ( I ), showing the formation of chains along [010] built from hydrogen bonds represented as dashed lines. H atoms not involved in hydrogen bonding have been omitted for clarity. [Symmetry code: (i) x, y-1, z]


(RS)-1-[5-(2-Chloro-prop-yl)indolin-1-yl]ethanone.

Yang XM - Acta Crystallogr Sect E Struct Rep Online (2010)

Partial packing view of compound ( I ), showing the formation of chains along [010] built from hydrogen bonds represented as dashed lines. H atoms not involved in hydrogen bonding have been omitted for clarity. [Symmetry code: (i) x, y-1, z]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050396&req=5

Fap2: Partial packing view of compound ( I ), showing the formation of chains along [010] built from hydrogen bonds represented as dashed lines. H atoms not involved in hydrogen bonding have been omitted for clarity. [Symmetry code: (i) x, y-1, z]
Bottom Line: Indeed, the Cl and CH(3) groups located on the stereogenic carbon exchange with each other.The whole crystal is a racemate.Non-classical C-H⋯O hydrogen bonds between symmetry-related benzene rings stabilize the crystal structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Guangdong Medical College, Dongguan 523808, People's Republic of China.

ABSTRACT
In the title compound, C(13)H(16)ClNO, the acetyl-indoline moiety is roughly planar (r.m.s. deviation = 0.0048 Å). The chloro-propyl group is out of the plane and is statistically disordered over two positions. Indeed, the Cl and CH(3) groups located on the stereogenic carbon exchange with each other. The whole crystal is a racemate. Non-classical C-H⋯O hydrogen bonds between symmetry-related benzene rings stabilize the crystal structure.

No MeSH data available.