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(RS)-1-[5-(2-Chloro-prop-yl)indolin-1-yl]ethanone.

Yang XM - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: Indeed, the Cl and CH(3) groups located on the stereogenic carbon exchange with each other.The whole crystal is a racemate.Non-classical C-H⋯O hydrogen bonds between symmetry-related benzene rings stabilize the crystal structure.

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Affiliation: Department of Chemistry, Guangdong Medical College, Dongguan 523808, People's Republic of China.

ABSTRACT
In the title compound, C(13)H(16)ClNO, the acetyl-indoline moiety is roughly planar (r.m.s. deviation = 0.0048 Å). The chloro-propyl group is out of the plane and is statistically disordered over two positions. Indeed, the Cl and CH(3) groups located on the stereogenic carbon exchange with each other. The whole crystal is a racemate. Non-classical C-H⋯O hydrogen bonds between symmetry-related benzene rings stabilize the crystal structure.

No MeSH data available.


Molecular view of (I) with the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small spheres of arbitrary radii. Only one component of the disorder is shown in the figure for the sake of clarity.
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Fap1: Molecular view of (I) with the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small spheres of arbitrary radii. Only one component of the disorder is shown in the figure for the sake of clarity.


(RS)-1-[5-(2-Chloro-prop-yl)indolin-1-yl]ethanone.

Yang XM - Acta Crystallogr Sect E Struct Rep Online (2010)

Molecular view of (I) with the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small spheres of arbitrary radii. Only one component of the disorder is shown in the figure for the sake of clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050396&req=5

Fap1: Molecular view of (I) with the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small spheres of arbitrary radii. Only one component of the disorder is shown in the figure for the sake of clarity.
Bottom Line: Indeed, the Cl and CH(3) groups located on the stereogenic carbon exchange with each other.The whole crystal is a racemate.Non-classical C-H⋯O hydrogen bonds between symmetry-related benzene rings stabilize the crystal structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Guangdong Medical College, Dongguan 523808, People's Republic of China.

ABSTRACT
In the title compound, C(13)H(16)ClNO, the acetyl-indoline moiety is roughly planar (r.m.s. deviation = 0.0048 Å). The chloro-propyl group is out of the plane and is statistically disordered over two positions. Indeed, the Cl and CH(3) groups located on the stereogenic carbon exchange with each other. The whole crystal is a racemate. Non-classical C-H⋯O hydrogen bonds between symmetry-related benzene rings stabilize the crystal structure.

No MeSH data available.