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Bis(μ-3,5-dinitro-benzoato-κO:O)bis-(μ-3,5-dinitro-benzoato)-κO,O:O;κO:O,O-bis-[(3,5-dinitro-benzoato-κO,O)(1,10-phenanthroline-κN,N)dysprosium(III)].

Dong CH, Zhang DH, Ren N, Xi GQ, Hao JJ - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the binuclear title complex, [Dy(2)(C(7)H(3)N(2)O(6))(6)(C(12)H(8)N(2))(2)], the Dy(III) ions exhibit a distorted monocapped square-anti-prismatic geometry and are coordinated by seven O atoms of four 3,5-dinitrobenzoate (DNBA) anions and two N atoms of a phenanthroline ligand.The carboxylate groups of the DNBA anions exhibit three coordination modes: bidentate chelating, bidentate chelating-bridging and tridentate chelating-bridging.The center of the mol-ecule is located on a crystallographic center of inversion.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Handan College, Handan, Hebei 056005, People's Republic of China.

ABSTRACT
In the binuclear title complex, [Dy(2)(C(7)H(3)N(2)O(6))(6)(C(12)H(8)N(2))(2)], the Dy(III) ions exhibit a distorted monocapped square-anti-prismatic geometry and are coordinated by seven O atoms of four 3,5-dinitrobenzoate (DNBA) anions and two N atoms of a phenanthroline ligand. The carboxylate groups of the DNBA anions exhibit three coordination modes: bidentate chelating, bidentate chelating-bridging and tridentate chelating-bridging. The center of the mol-ecule is located on a crystallographic center of inversion.

No MeSH data available.


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Molecular structure of the title compound with the atom-labelling scheme.
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Fap1: Molecular structure of the title compound with the atom-labelling scheme.


Bis(μ-3,5-dinitro-benzoato-κO:O)bis-(μ-3,5-dinitro-benzoato)-κO,O:O;κO:O,O-bis-[(3,5-dinitro-benzoato-κO,O)(1,10-phenanthroline-κN,N)dysprosium(III)].

Dong CH, Zhang DH, Ren N, Xi GQ, Hao JJ - Acta Crystallogr Sect E Struct Rep Online (2010)

Molecular structure of the title compound with the atom-labelling scheme.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050390&req=5

Fap1: Molecular structure of the title compound with the atom-labelling scheme.
Bottom Line: In the binuclear title complex, [Dy(2)(C(7)H(3)N(2)O(6))(6)(C(12)H(8)N(2))(2)], the Dy(III) ions exhibit a distorted monocapped square-anti-prismatic geometry and are coordinated by seven O atoms of four 3,5-dinitrobenzoate (DNBA) anions and two N atoms of a phenanthroline ligand.The carboxylate groups of the DNBA anions exhibit three coordination modes: bidentate chelating, bidentate chelating-bridging and tridentate chelating-bridging.The center of the mol-ecule is located on a crystallographic center of inversion.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Handan College, Handan, Hebei 056005, People's Republic of China.

ABSTRACT
In the binuclear title complex, [Dy(2)(C(7)H(3)N(2)O(6))(6)(C(12)H(8)N(2))(2)], the Dy(III) ions exhibit a distorted monocapped square-anti-prismatic geometry and are coordinated by seven O atoms of four 3,5-dinitrobenzoate (DNBA) anions and two N atoms of a phenanthroline ligand. The carboxylate groups of the DNBA anions exhibit three coordination modes: bidentate chelating, bidentate chelating-bridging and tridentate chelating-bridging. The center of the mol-ecule is located on a crystallographic center of inversion.

No MeSH data available.


Related in: MedlinePlus