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(η-Benzene){2-[2-(tert-butyl-sulfan-yl)phenyl]pyridine-κN,S}chlorido-ruthenium(II) hexa-fluorido-phosphate.

Hirotsu M, Yogi A, Kinoshita I - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title compound, [RuCl(C(6)H(6))(C(15)H(17)NS)]PF(6), the cation adopts a three-legged piano-stool structure around the Ru(II) atom with an η(6)-benzene ligand, a chloride ligand and a 2-[2-(tert-butyl-sulfan-yl)phen-yl]pyridine (btppy) ligand.The btppy ligand acts as a N,S-bidentate ligand, forming a six-membered ring, which has an envelope conformation.The unit cell contains two pairs of racemic diastereomers with (S(Ru),S(S)) and (R(Ru),R(S)) configurations, in which the tert-butyl group on the coordin-ated S atom is distant from the η(6)-benzene ligand.

View Article: PubMed Central - HTML - PubMed

Affiliation: Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan.

ABSTRACT
In the title compound, [RuCl(C(6)H(6))(C(15)H(17)NS)]PF(6), the cation adopts a three-legged piano-stool structure around the Ru(II) atom with an η(6)-benzene ligand, a chloride ligand and a 2-[2-(tert-butyl-sulfan-yl)phen-yl]pyridine (btppy) ligand. The btppy ligand acts as a N,S-bidentate ligand, forming a six-membered ring, which has an envelope conformation. The S-Ru-N bite angle is 86.76 (9)°, and the dihedral angle between the pyridine and benzene rings in btppy is 39.8 (2)°. The unit cell contains two pairs of racemic diastereomers with (S(Ru),S(S)) and (R(Ru),R(S)) configurations, in which the tert-butyl group on the coordin-ated S atom is distant from the η(6)-benzene ligand.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of (I) with numbering scheme. Displacement ellipsoids are drawn at the 40% probability level.
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Fap1: The molecular structure of (I) with numbering scheme. Displacement ellipsoids are drawn at the 40% probability level.


(η-Benzene){2-[2-(tert-butyl-sulfan-yl)phenyl]pyridine-κN,S}chlorido-ruthenium(II) hexa-fluorido-phosphate.

Hirotsu M, Yogi A, Kinoshita I - Acta Crystallogr Sect E Struct Rep Online (2010)

The molecular structure of (I) with numbering scheme. Displacement ellipsoids are drawn at the 40% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050383&req=5

Fap1: The molecular structure of (I) with numbering scheme. Displacement ellipsoids are drawn at the 40% probability level.
Bottom Line: In the title compound, [RuCl(C(6)H(6))(C(15)H(17)NS)]PF(6), the cation adopts a three-legged piano-stool structure around the Ru(II) atom with an η(6)-benzene ligand, a chloride ligand and a 2-[2-(tert-butyl-sulfan-yl)phen-yl]pyridine (btppy) ligand.The btppy ligand acts as a N,S-bidentate ligand, forming a six-membered ring, which has an envelope conformation.The unit cell contains two pairs of racemic diastereomers with (S(Ru),S(S)) and (R(Ru),R(S)) configurations, in which the tert-butyl group on the coordin-ated S atom is distant from the η(6)-benzene ligand.

View Article: PubMed Central - HTML - PubMed

Affiliation: Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan.

ABSTRACT
In the title compound, [RuCl(C(6)H(6))(C(15)H(17)NS)]PF(6), the cation adopts a three-legged piano-stool structure around the Ru(II) atom with an η(6)-benzene ligand, a chloride ligand and a 2-[2-(tert-butyl-sulfan-yl)phen-yl]pyridine (btppy) ligand. The btppy ligand acts as a N,S-bidentate ligand, forming a six-membered ring, which has an envelope conformation. The S-Ru-N bite angle is 86.76 (9)°, and the dihedral angle between the pyridine and benzene rings in btppy is 39.8 (2)°. The unit cell contains two pairs of racemic diastereomers with (S(Ru),S(S)) and (R(Ru),R(S)) configurations, in which the tert-butyl group on the coordin-ated S atom is distant from the η(6)-benzene ligand.

No MeSH data available.


Related in: MedlinePlus