Limits...
(1S,2R,4S)-1-[(Benzyl-amino)-meth-yl]-4-(prop-1-en-2-yl)cyclo-hexane-1,2-diol.

Outouch R, Boualy B, Ali MA, Firdoussi LE, Rizzoli C - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The mol-ecular conformation is stabilized by an intra-molecular O-H⋯N hydrogen bond.In the crystal, mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds, forming chains parallel to the a axis, which are further connected by O-H⋯O hydrogen bonds into sheets parallel to (010).The absolute configuration of the mol-ecule is known from the synthetic procedure.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(17)H(25)NO(2), was synthesized by epoxidation of the double bond of (S)-perillyl alcohol [(S)-4-isopropenyl-1-cyclo-hexenyl-methanol], followed by the oxirane ring-opening by benzyl-amine using [Ca(CF(3)CO(2))(2)] as catalyst under solvent-free condition at 313 K. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯N hydrogen bond. In the crystal, mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds, forming chains parallel to the a axis, which are further connected by O-H⋯O hydrogen bonds into sheets parallel to (010). The absolute configuration of the mol-ecule is known from the synthetic procedure.

No MeSH data available.


The molecular structure of the title compound, with displacement ellipsoids drawn at the 40% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3050382&req=5

Fap1: The molecular structure of the title compound, with displacement ellipsoids drawn at the 40% probability level.


(1S,2R,4S)-1-[(Benzyl-amino)-meth-yl]-4-(prop-1-en-2-yl)cyclo-hexane-1,2-diol.

Outouch R, Boualy B, Ali MA, Firdoussi LE, Rizzoli C - Acta Crystallogr Sect E Struct Rep Online (2010)

The molecular structure of the title compound, with displacement ellipsoids drawn at the 40% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050382&req=5

Fap1: The molecular structure of the title compound, with displacement ellipsoids drawn at the 40% probability level.
Bottom Line: The mol-ecular conformation is stabilized by an intra-molecular O-H⋯N hydrogen bond.In the crystal, mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds, forming chains parallel to the a axis, which are further connected by O-H⋯O hydrogen bonds into sheets parallel to (010).The absolute configuration of the mol-ecule is known from the synthetic procedure.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(17)H(25)NO(2), was synthesized by epoxidation of the double bond of (S)-perillyl alcohol [(S)-4-isopropenyl-1-cyclo-hexenyl-methanol], followed by the oxirane ring-opening by benzyl-amine using [Ca(CF(3)CO(2))(2)] as catalyst under solvent-free condition at 313 K. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯N hydrogen bond. In the crystal, mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds, forming chains parallel to the a axis, which are further connected by O-H⋯O hydrogen bonds into sheets parallel to (010). The absolute configuration of the mol-ecule is known from the synthetic procedure.

No MeSH data available.