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Methyl (2Z)-3-[(4-nitro-phen-yl)carbamo-yl]prop-2-enoate.

Munawar KS, Ali S, Tahir MN - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: This results in a short intra-molecular O =C⋯O=C contact of 2.7201 (17) Å between the amide O atom and the ester carbonyl C atom.An intra-molecular C-H⋯O inter-action between the benzene ring and the amide group generates an S(6) ring motif.Inter-molecular C-H⋯O and N-H⋯O hydrogen bonds complete R(2) (2)(11) ring motifs and join mol-ecules into [100] chains.

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ABSTRACT
In the title compound, C(11)H(10)N(2)O(5), the amide group is nearly coplanar and the ester group approximately perpendicular to the vinyl C-HC=CH-C group [dihedral angles of 5.0 (2) and 88.89 (5)°, respectively]. This results in a short intra-molecular O =C⋯O=C contact of 2.7201 (17) Å between the amide O atom and the ester carbonyl C atom. The prop-2-enamide fragment and the nitro group make dihedral angles of 20.42 (6) and 13.54 (17)°, respectively, with the benzene ring. An intra-molecular C-H⋯O inter-action between the benzene ring and the amide group generates an S(6) ring motif. Inter-molecular C-H⋯O and N-H⋯O hydrogen bonds complete R(2) (2)(11) ring motifs and join mol-ecules into [100] chains.

No MeSH data available.


View of the title compound with the atom numbering scheme. The displacement ellipsoids are drawn at the 50% probability level. H atoms are shown by small circles of arbitrary radii. The dotted line shows intramolecular hydrogen bond.
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Fap1: View of the title compound with the atom numbering scheme. The displacement ellipsoids are drawn at the 50% probability level. H atoms are shown by small circles of arbitrary radii. The dotted line shows intramolecular hydrogen bond.


Methyl (2Z)-3-[(4-nitro-phen-yl)carbamo-yl]prop-2-enoate.

Munawar KS, Ali S, Tahir MN - Acta Crystallogr Sect E Struct Rep Online (2010)

View of the title compound with the atom numbering scheme. The displacement ellipsoids are drawn at the 50% probability level. H atoms are shown by small circles of arbitrary radii. The dotted line shows intramolecular hydrogen bond.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050372&req=5

Fap1: View of the title compound with the atom numbering scheme. The displacement ellipsoids are drawn at the 50% probability level. H atoms are shown by small circles of arbitrary radii. The dotted line shows intramolecular hydrogen bond.
Bottom Line: This results in a short intra-molecular O =C⋯O=C contact of 2.7201 (17) Å between the amide O atom and the ester carbonyl C atom.An intra-molecular C-H⋯O inter-action between the benzene ring and the amide group generates an S(6) ring motif.Inter-molecular C-H⋯O and N-H⋯O hydrogen bonds complete R(2) (2)(11) ring motifs and join mol-ecules into [100] chains.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(11)H(10)N(2)O(5), the amide group is nearly coplanar and the ester group approximately perpendicular to the vinyl C-HC=CH-C group [dihedral angles of 5.0 (2) and 88.89 (5)°, respectively]. This results in a short intra-molecular O =C⋯O=C contact of 2.7201 (17) Å between the amide O atom and the ester carbonyl C atom. The prop-2-enamide fragment and the nitro group make dihedral angles of 20.42 (6) and 13.54 (17)°, respectively, with the benzene ring. An intra-molecular C-H⋯O inter-action between the benzene ring and the amide group generates an S(6) ring motif. Inter-molecular C-H⋯O and N-H⋯O hydrogen bonds complete R(2) (2)(11) ring motifs and join mol-ecules into [100] chains.

No MeSH data available.