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catena-Poly[[[aqua-(pyridine-4-carboxyl-ato-κN)silver(I)]-μ-hexa-methyl-ene-tetra-amine-κN:N'] dihydrate].

Sun D, Han L, Zang H - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title compound, {[Ag(C(6)H(4)NO(2))(C(6)H(12)N(4))(H(2)O)]·2H(2)O}(n), the Ag(I) atom shows a distorted triangular pyramidal geometry,, formed by two N atoms from two hexa-methyl-ene-tetra-amine (hmt) ligands and one N atom from a pyridine-4-carboxyl-ate (4-pdc) ligand and one water mol-ecule.The carboxyl-ate group of the 4-pdc ligand is uncoordinated.O-H⋯O hydrogen bonds between the water mol-ecules and carboxyl-ate groups stabilize the structure.

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ABSTRACT
In the title compound, {[Ag(C(6)H(4)NO(2))(C(6)H(12)N(4))(H(2)O)]·2H(2)O}(n), the Ag(I) atom shows a distorted triangular pyramidal geometry,, formed by two N atoms from two hexa-methyl-ene-tetra-amine (hmt) ligands and one N atom from a pyridine-4-carboxyl-ate (4-pdc) ligand and one water mol-ecule. The hmt ligands bridge the Ag atoms, forming a chain along [001]. The carboxyl-ate group of the 4-pdc ligand is uncoordinated. O-H⋯O hydrogen bonds between the water mol-ecules and carboxyl-ate groups stabilize the structure.

No MeSH data available.


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View of the chain structure in the title compound.
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Fap2: View of the chain structure in the title compound.


catena-Poly[[[aqua-(pyridine-4-carboxyl-ato-κN)silver(I)]-μ-hexa-methyl-ene-tetra-amine-κN:N'] dihydrate].

Sun D, Han L, Zang H - Acta Crystallogr Sect E Struct Rep Online (2010)

View of the chain structure in the title compound.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050371&req=5

Fap2: View of the chain structure in the title compound.
Bottom Line: In the title compound, {[Ag(C(6)H(4)NO(2))(C(6)H(12)N(4))(H(2)O)]·2H(2)O}(n), the Ag(I) atom shows a distorted triangular pyramidal geometry,, formed by two N atoms from two hexa-methyl-ene-tetra-amine (hmt) ligands and one N atom from a pyridine-4-carboxyl-ate (4-pdc) ligand and one water mol-ecule.The carboxyl-ate group of the 4-pdc ligand is uncoordinated.O-H⋯O hydrogen bonds between the water mol-ecules and carboxyl-ate groups stabilize the structure.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, {[Ag(C(6)H(4)NO(2))(C(6)H(12)N(4))(H(2)O)]·2H(2)O}(n), the Ag(I) atom shows a distorted triangular pyramidal geometry,, formed by two N atoms from two hexa-methyl-ene-tetra-amine (hmt) ligands and one N atom from a pyridine-4-carboxyl-ate (4-pdc) ligand and one water mol-ecule. The hmt ligands bridge the Ag atoms, forming a chain along [001]. The carboxyl-ate group of the 4-pdc ligand is uncoordinated. O-H⋯O hydrogen bonds between the water mol-ecules and carboxyl-ate groups stabilize the structure.

No MeSH data available.


Related in: MedlinePlus