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Bis{2-[3-(dimethyl-amino)-propyl-imino-meth-yl]-6-meth-oxy-phenolato}-κN,N',O;κN,O-zinc(II) dihydrate.

Lin H, Wang XJ - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal-bipyramidal environment.One O and two N atoms constitute the base of the pyramid, and one O and one N atoms occupy the apical positions.Inter-molecular O-H⋯O and O-H⋯N hydrogen bonds between the lattice water mol-ecules and N/O atoms of the Schiff base ligands stabilize the conformation, whereas inter-molecular O-H⋯O hydrogen bonds between the two lattice water mol-ecules lead to a chain structure in [001].

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ABSTRACT
In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal-bipyramidal environment. One O and two N atoms constitute the base of the pyramid, and one O and one N atoms occupy the apical positions. Inter-molecular O-H⋯O and O-H⋯N hydrogen bonds between the lattice water mol-ecules and N/O atoms of the Schiff base ligands stabilize the conformation, whereas inter-molecular O-H⋯O hydrogen bonds between the two lattice water mol-ecules lead to a chain structure in [001].

No MeSH data available.


A view of the one-dimensional chain structure of (I). The hydrogen bond interactions are depicted by dashed lines.
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Fap2: A view of the one-dimensional chain structure of (I). The hydrogen bond interactions are depicted by dashed lines.


Bis{2-[3-(dimethyl-amino)-propyl-imino-meth-yl]-6-meth-oxy-phenolato}-κN,N',O;κN,O-zinc(II) dihydrate.

Lin H, Wang XJ - Acta Crystallogr Sect E Struct Rep Online (2010)

A view of the one-dimensional chain structure of (I). The hydrogen bond interactions are depicted by dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050366&req=5

Fap2: A view of the one-dimensional chain structure of (I). The hydrogen bond interactions are depicted by dashed lines.
Bottom Line: In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal-bipyramidal environment.One O and two N atoms constitute the base of the pyramid, and one O and one N atoms occupy the apical positions.Inter-molecular O-H⋯O and O-H⋯N hydrogen bonds between the lattice water mol-ecules and N/O atoms of the Schiff base ligands stabilize the conformation, whereas inter-molecular O-H⋯O hydrogen bonds between the two lattice water mol-ecules lead to a chain structure in [001].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal-bipyramidal environment. One O and two N atoms constitute the base of the pyramid, and one O and one N atoms occupy the apical positions. Inter-molecular O-H⋯O and O-H⋯N hydrogen bonds between the lattice water mol-ecules and N/O atoms of the Schiff base ligands stabilize the conformation, whereas inter-molecular O-H⋯O hydrogen bonds between the two lattice water mol-ecules lead to a chain structure in [001].

No MeSH data available.