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trans-Bis(dimethyl sulfoxide-κO)bis-(thio-semicarbazide-κN,S)cadmium dipicrate dihydrate.

Shanthakumari R, Hema R, Ramamurthy K, Stoeckli-Evans H - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: It is hexa-coordinated in an octahedral fashion by two thio-semicarbazide mol-ecules, which coordinate in a bidentate manner via the S and N atoms, and to the O atom of two dimethyl sufoxide (DMSO) mol-ecules.The charges are equilibrated by two picrate anions and the complex crystallizes as a dihydrate.In the crystal, these units are linked by a number of O-H⋯O and N-H⋯S hydrogen bonds and weak C-H⋯O inter-actions, forming a three-dimensional network.

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ABSTRACT
In the cation of the title compound, [Cd(CH(5)N(3)S)(2)(C(2)H(6)OS)(2)](C(6)H(2)N(3)O(7))(2)·2H(2)O, the Cd(II) atom is located on an inversion center. It is hexa-coordinated in an octahedral fashion by two thio-semicarbazide mol-ecules, which coordinate in a bidentate manner via the S and N atoms, and to the O atom of two dimethyl sufoxide (DMSO) mol-ecules. The charges are equilibrated by two picrate anions and the complex crystallizes as a dihydrate. In the crystal, these units are linked by a number of O-H⋯O and N-H⋯S hydrogen bonds and weak C-H⋯O inter-actions, forming a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus

A view along the a axis of the crystal packing of the title compound. The hydrogen bonds are shown as dashed lines (see Table 1 for details; C-bound H-atoms not involved in C—H···O interactions have been omitted for clarity].
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Fap2: A view along the a axis of the crystal packing of the title compound. The hydrogen bonds are shown as dashed lines (see Table 1 for details; C-bound H-atoms not involved in C—H···O interactions have been omitted for clarity].


trans-Bis(dimethyl sulfoxide-κO)bis-(thio-semicarbazide-κN,S)cadmium dipicrate dihydrate.

Shanthakumari R, Hema R, Ramamurthy K, Stoeckli-Evans H - Acta Crystallogr Sect E Struct Rep Online (2010)

A view along the a axis of the crystal packing of the title compound. The hydrogen bonds are shown as dashed lines (see Table 1 for details; C-bound H-atoms not involved in C—H···O interactions have been omitted for clarity].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050361&req=5

Fap2: A view along the a axis of the crystal packing of the title compound. The hydrogen bonds are shown as dashed lines (see Table 1 for details; C-bound H-atoms not involved in C—H···O interactions have been omitted for clarity].
Bottom Line: It is hexa-coordinated in an octahedral fashion by two thio-semicarbazide mol-ecules, which coordinate in a bidentate manner via the S and N atoms, and to the O atom of two dimethyl sufoxide (DMSO) mol-ecules.The charges are equilibrated by two picrate anions and the complex crystallizes as a dihydrate.In the crystal, these units are linked by a number of O-H⋯O and N-H⋯S hydrogen bonds and weak C-H⋯O inter-actions, forming a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the cation of the title compound, [Cd(CH(5)N(3)S)(2)(C(2)H(6)OS)(2)](C(6)H(2)N(3)O(7))(2)·2H(2)O, the Cd(II) atom is located on an inversion center. It is hexa-coordinated in an octahedral fashion by two thio-semicarbazide mol-ecules, which coordinate in a bidentate manner via the S and N atoms, and to the O atom of two dimethyl sufoxide (DMSO) mol-ecules. The charges are equilibrated by two picrate anions and the complex crystallizes as a dihydrate. In the crystal, these units are linked by a number of O-H⋯O and N-H⋯S hydrogen bonds and weak C-H⋯O inter-actions, forming a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus