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Tris(methylammonium thiocyanurate) monohydrate.

Hou Y, Yang Y - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The third independent anion and the water mol-ecule form a chain by way of N-H⋯S and O-H⋯S contacts, which propagates parallel to the ribbon.The chains and ribbons are cross-linked by O-H⋯S hydrogen bonds, generating sheets.The three independent trimethyl-ammonium cations are contained between the sheets by way of various N-H⋯S and N-H⋯N contacts.

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ABSTRACT
In the title compound, 3[(CH(3))(3)HN(+)]·3C(3)H(2)N(3)S(3) (-)·H(2)O, two independent trithio-cyanurate anions construct a planar hydrogen-bonded ribbon with two N-H⋯S hydrogen bonds linking each pair of adjacent anions in the chain. The third independent anion and the water mol-ecule form a chain by way of N-H⋯S and O-H⋯S contacts, which propagates parallel to the ribbon. The chains and ribbons are cross-linked by O-H⋯S hydrogen bonds, generating sheets. The three independent trimethyl-ammonium cations are contained between the sheets by way of various N-H⋯S and N-H⋯N contacts.

No MeSH data available.


Hydrogen-bonded linking pattern of the separated unit in the crystal structure of the title compound.
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Fap2: Hydrogen-bonded linking pattern of the separated unit in the crystal structure of the title compound.


Tris(methylammonium thiocyanurate) monohydrate.

Hou Y, Yang Y - Acta Crystallogr Sect E Struct Rep Online (2010)

Hydrogen-bonded linking pattern of the separated unit in the crystal structure of the title compound.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050359&req=5

Fap2: Hydrogen-bonded linking pattern of the separated unit in the crystal structure of the title compound.
Bottom Line: The third independent anion and the water mol-ecule form a chain by way of N-H⋯S and O-H⋯S contacts, which propagates parallel to the ribbon.The chains and ribbons are cross-linked by O-H⋯S hydrogen bonds, generating sheets.The three independent trimethyl-ammonium cations are contained between the sheets by way of various N-H⋯S and N-H⋯N contacts.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, 3[(CH(3))(3)HN(+)]·3C(3)H(2)N(3)S(3) (-)·H(2)O, two independent trithio-cyanurate anions construct a planar hydrogen-bonded ribbon with two N-H⋯S hydrogen bonds linking each pair of adjacent anions in the chain. The third independent anion and the water mol-ecule form a chain by way of N-H⋯S and O-H⋯S contacts, which propagates parallel to the ribbon. The chains and ribbons are cross-linked by O-H⋯S hydrogen bonds, generating sheets. The three independent trimethyl-ammonium cations are contained between the sheets by way of various N-H⋯S and N-H⋯N contacts.

No MeSH data available.