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[2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N']bis-(thio-cyanato-κN)cadmium(II).

Zheng LY, Chi YH - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The dihedral angles formed between the mean planes of the pyrazole rings and the phenanthroline system are 15.74 (15) and 16.30 (13)°.In the crystal, there is a π-π stacking inter-action involving two symmetry-related pyrazole rings, with a centroid-centroid distance of 3.664 (3) Å.In addition, there is a relatively short inter-molecular contact between C atoms [C⋯C = 3.399 (6) Å] involving symmetry-related pyridine rings along the a axis.

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ABSTRACT
In the title complex, [Cd(NCS)(2)(C(22)H(20)N(6))], the Cd(II) ion is in a CdN(6) coordination geometry which is inter-mediate between octa-hedral and trigonal-prismatic. The dihedral angles formed between the mean planes of the pyrazole rings and the phenanthroline system are 15.74 (15) and 16.30 (13)°. In the crystal, there is a π-π stacking inter-action involving two symmetry-related pyrazole rings, with a centroid-centroid distance of 3.664 (3) Å. In addition, there is a relatively short inter-molecular contact between C atoms [C⋯C = 3.399 (6) Å] involving symmetry-related pyridine rings along the a axis.

No MeSH data available.


Related in: MedlinePlus

Part of the crystal structure with short C···C contacts drawn as dashed lines.
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Fap2: Part of the crystal structure with short C···C contacts drawn as dashed lines.


[2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N']bis-(thio-cyanato-κN)cadmium(II).

Zheng LY, Chi YH - Acta Crystallogr Sect E Struct Rep Online (2010)

Part of the crystal structure with short C···C contacts drawn as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050342&req=5

Fap2: Part of the crystal structure with short C···C contacts drawn as dashed lines.
Bottom Line: The dihedral angles formed between the mean planes of the pyrazole rings and the phenanthroline system are 15.74 (15) and 16.30 (13)°.In the crystal, there is a π-π stacking inter-action involving two symmetry-related pyrazole rings, with a centroid-centroid distance of 3.664 (3) Å.In addition, there is a relatively short inter-molecular contact between C atoms [C⋯C = 3.399 (6) Å] involving symmetry-related pyridine rings along the a axis.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title complex, [Cd(NCS)(2)(C(22)H(20)N(6))], the Cd(II) ion is in a CdN(6) coordination geometry which is inter-mediate between octa-hedral and trigonal-prismatic. The dihedral angles formed between the mean planes of the pyrazole rings and the phenanthroline system are 15.74 (15) and 16.30 (13)°. In the crystal, there is a π-π stacking inter-action involving two symmetry-related pyrazole rings, with a centroid-centroid distance of 3.664 (3) Å. In addition, there is a relatively short inter-molecular contact between C atoms [C⋯C = 3.399 (6) Å] involving symmetry-related pyridine rings along the a axis.

No MeSH data available.


Related in: MedlinePlus