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Bis{N,N-bis-[(diphenyl-phosphan-yl)meth-yl]aniline-κP,P'}copper(I) tetra-fluoridoborate.

Shang J, Huang LL, Huang TH, Ma K, Ni QL - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the cation of the title compound, [Cu(C(32)H(29)NP(2))(2)]BF(4), the Cu(I) atom is four-coordinated in a distorted tetra-hedral geometry by four P atoms from two N,N-bis-[(diphenyl-phosphan-yl)meth-yl]aniline ligands.In the crystal, the cations are linked by C-H⋯π inter-actions, forming chains along the a axis.Intra-molecular C-H⋯N and inter-molecular C-H⋯F hydrogen bonds are also observed.

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ABSTRACT
In the cation of the title compound, [Cu(C(32)H(29)NP(2))(2)]BF(4), the Cu(I) atom is four-coordinated in a distorted tetra-hedral geometry by four P atoms from two N,N-bis-[(diphenyl-phosphan-yl)meth-yl]aniline ligands. In the crystal, the cations are linked by C-H⋯π inter-actions, forming chains along the a axis. Intra-molecular C-H⋯N and inter-molecular C-H⋯F hydrogen bonds are also observed.

No MeSH data available.


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Partial crystal packing of the title compound showing the chains of cations parallel to the a axis. C—H···π interactions are shown as dashed lines.
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Fap2: Partial crystal packing of the title compound showing the chains of cations parallel to the a axis. C—H···π interactions are shown as dashed lines.


Bis{N,N-bis-[(diphenyl-phosphan-yl)meth-yl]aniline-κP,P'}copper(I) tetra-fluoridoborate.

Shang J, Huang LL, Huang TH, Ma K, Ni QL - Acta Crystallogr Sect E Struct Rep Online (2010)

Partial crystal packing of the title compound showing the chains of cations parallel to the a axis. C—H···π interactions are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050340&req=5

Fap2: Partial crystal packing of the title compound showing the chains of cations parallel to the a axis. C—H···π interactions are shown as dashed lines.
Bottom Line: In the cation of the title compound, [Cu(C(32)H(29)NP(2))(2)]BF(4), the Cu(I) atom is four-coordinated in a distorted tetra-hedral geometry by four P atoms from two N,N-bis-[(diphenyl-phosphan-yl)meth-yl]aniline ligands.In the crystal, the cations are linked by C-H⋯π inter-actions, forming chains along the a axis.Intra-molecular C-H⋯N and inter-molecular C-H⋯F hydrogen bonds are also observed.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the cation of the title compound, [Cu(C(32)H(29)NP(2))(2)]BF(4), the Cu(I) atom is four-coordinated in a distorted tetra-hedral geometry by four P atoms from two N,N-bis-[(diphenyl-phosphan-yl)meth-yl]aniline ligands. In the crystal, the cations are linked by C-H⋯π inter-actions, forming chains along the a axis. Intra-molecular C-H⋯N and inter-molecular C-H⋯F hydrogen bonds are also observed.

No MeSH data available.


Related in: MedlinePlus