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catena-Poly[triethyl-ammonium [[triphenyl-tin(IV)]-μ-3,3'-dihydroxy-4,4'-methyl-ene-di-2-naphtho-ato]].

Liu L, Gong S - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The title compound, {(C(6)H(16)N)[Sn(C(6)H(5))(3)(C(23)H(14)O(6))]}(n), has an infinite chain structure, formed through monodentate carboxyl-ate groups of the pamoic acid anion.Et(3)NH(+) cations are inserted between the chains.The coordination of the Sn(IV) atom is completed by three phenyl ligands, giving a distorted trigonal-bipyramidal geometry.

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ABSTRACT
The title compound, {(C(6)H(16)N)[Sn(C(6)H(5))(3)(C(23)H(14)O(6))]}(n), has an infinite chain structure, formed through monodentate carboxyl-ate groups of the pamoic acid anion. The anion bridges two symmetry-related Sn(IV) ions and the resulting polymeric chains are parallel to [201] in the crystal. Et(3)NH(+) cations are inserted between the chains. The coordination of the Sn(IV) atom is completed by three phenyl ligands, giving a distorted trigonal-bipyramidal geometry.

No MeSH data available.


The molecular structure of the compound, showing 30% probability displacement ellipsoids.
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Fap1: The molecular structure of the compound, showing 30% probability displacement ellipsoids.


catena-Poly[triethyl-ammonium [[triphenyl-tin(IV)]-μ-3,3'-dihydroxy-4,4'-methyl-ene-di-2-naphtho-ato]].

Liu L, Gong S - Acta Crystallogr Sect E Struct Rep Online (2010)

The molecular structure of the compound, showing 30% probability displacement ellipsoids.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050292&req=5

Fap1: The molecular structure of the compound, showing 30% probability displacement ellipsoids.
Bottom Line: The title compound, {(C(6)H(16)N)[Sn(C(6)H(5))(3)(C(23)H(14)O(6))]}(n), has an infinite chain structure, formed through monodentate carboxyl-ate groups of the pamoic acid anion.Et(3)NH(+) cations are inserted between the chains.The coordination of the Sn(IV) atom is completed by three phenyl ligands, giving a distorted trigonal-bipyramidal geometry.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, {(C(6)H(16)N)[Sn(C(6)H(5))(3)(C(23)H(14)O(6))]}(n), has an infinite chain structure, formed through monodentate carboxyl-ate groups of the pamoic acid anion. The anion bridges two symmetry-related Sn(IV) ions and the resulting polymeric chains are parallel to [201] in the crystal. Et(3)NH(+) cations are inserted between the chains. The coordination of the Sn(IV) atom is completed by three phenyl ligands, giving a distorted trigonal-bipyramidal geometry.

No MeSH data available.