Limits...
Bis[1-(3-cyano-benz-yl)pyridinium] bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).

Xian H, Duan HB - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The Ni(II) ion in the [Ni(mnt)(2)](2-) anion is coordinated by four S atoms of two mnt(2-) ligands, and exhibits square-planar coordination geometry.In the [CNBzPy](+) cation, the benzene and pyridine rings are twisted with respect to the C/C/N plane incorporating the methyl-ene C atom that links them.The crystal structure is stabilized by Coulombic inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Nanjing Xiaozhuang College, Nanjing 210017, People's Republic of China.

ABSTRACT
In the ionic title complex, (C(13)H(11)N(2))(2)[Ni(C(4)N(2)S(2))(2)], the Ni(II) ion is located on an inversion centre so the asymmetric unit contains one-half [Ni(mnt)(2)](2-) dianion (mnt(2-) is maleonitrile-dithiolate) and one 1-(3-cyano-benz-yl)pyridinium cation ([CNBzPy](+)). The Ni(II) ion in the [Ni(mnt)(2)](2-) anion is coordinated by four S atoms of two mnt(2-) ligands, and exhibits square-planar coordination geometry. In the [CNBzPy](+) cation, the benzene and pyridine rings are twisted with respect to the C/C/N plane incorporating the methyl-ene C atom that links them. The crystal structure is stabilized by Coulombic inter-actions.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of (I), showing the atom-numbering scheme and displacement ellipsoids at the 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3050285&req=5

Fap1: The molecular structure of (I), showing the atom-numbering scheme and displacement ellipsoids at the 30% probability level.


Bis[1-(3-cyano-benz-yl)pyridinium] bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).

Xian H, Duan HB - Acta Crystallogr Sect E Struct Rep Online (2010)

The molecular structure of (I), showing the atom-numbering scheme and displacement ellipsoids at the 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050285&req=5

Fap1: The molecular structure of (I), showing the atom-numbering scheme and displacement ellipsoids at the 30% probability level.
Bottom Line: The Ni(II) ion in the [Ni(mnt)(2)](2-) anion is coordinated by four S atoms of two mnt(2-) ligands, and exhibits square-planar coordination geometry.In the [CNBzPy](+) cation, the benzene and pyridine rings are twisted with respect to the C/C/N plane incorporating the methyl-ene C atom that links them.The crystal structure is stabilized by Coulombic inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Nanjing Xiaozhuang College, Nanjing 210017, People's Republic of China.

ABSTRACT
In the ionic title complex, (C(13)H(11)N(2))(2)[Ni(C(4)N(2)S(2))(2)], the Ni(II) ion is located on an inversion centre so the asymmetric unit contains one-half [Ni(mnt)(2)](2-) dianion (mnt(2-) is maleonitrile-dithiolate) and one 1-(3-cyano-benz-yl)pyridinium cation ([CNBzPy](+)). The Ni(II) ion in the [Ni(mnt)(2)](2-) anion is coordinated by four S atoms of two mnt(2-) ligands, and exhibits square-planar coordination geometry. In the [CNBzPy](+) cation, the benzene and pyridine rings are twisted with respect to the C/C/N plane incorporating the methyl-ene C atom that links them. The crystal structure is stabilized by Coulombic inter-actions.

No MeSH data available.


Related in: MedlinePlus