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The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4)).

Zhang E, Zhao S, Zhang J, Fu P, Yao J - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The asymmetric unit contains three Zn sites, three B-atom sites (all with symmetry 3), two P sites (both with m symmetry) and nine O-atom sites (four with m symmetry).The fundamental building units of the title structure are isolated BO(3) triangles and PO(4) tetra-hedra, which are bridged by ZnO(4) tetra-hedra or ZnO(5) trigonal bipyramids through common O atoms, leading to a three-dimensional framework structure.Some significant structural differences between the β-polymorph and the α-polymorph are discussed.

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ABSTRACT
Crystals of β-Zn(3)(BO(3))(PO(4)) have been grown by the Kyropoulos method. The asymmetric unit contains three Zn sites, three B-atom sites (all with symmetry 3), two P sites (both with m symmetry) and nine O-atom sites (four with m symmetry). The fundamental building units of the title structure are isolated BO(3) triangles and PO(4) tetra-hedra, which are bridged by ZnO(4) tetra-hedra or ZnO(5) trigonal bipyramids through common O atoms, leading to a three-dimensional framework structure. Some significant structural differences between the β-polymorph and the α-polymorph are discussed.

No MeSH data available.


The structure of β-Zn3(BO3)(PO4) viewed along [001].
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Fap3: The structure of β-Zn3(BO3)(PO4) viewed along [001].


The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4)).

Zhang E, Zhao S, Zhang J, Fu P, Yao J - Acta Crystallogr Sect E Struct Rep Online (2010)

The structure of β-Zn3(BO3)(PO4) viewed along [001].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050272&req=5

Fap3: The structure of β-Zn3(BO3)(PO4) viewed along [001].
Bottom Line: The asymmetric unit contains three Zn sites, three B-atom sites (all with symmetry 3), two P sites (both with m symmetry) and nine O-atom sites (four with m symmetry).The fundamental building units of the title structure are isolated BO(3) triangles and PO(4) tetra-hedra, which are bridged by ZnO(4) tetra-hedra or ZnO(5) trigonal bipyramids through common O atoms, leading to a three-dimensional framework structure.Some significant structural differences between the β-polymorph and the α-polymorph are discussed.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
Crystals of β-Zn(3)(BO(3))(PO(4)) have been grown by the Kyropoulos method. The asymmetric unit contains three Zn sites, three B-atom sites (all with symmetry 3), two P sites (both with m symmetry) and nine O-atom sites (four with m symmetry). The fundamental building units of the title structure are isolated BO(3) triangles and PO(4) tetra-hedra, which are bridged by ZnO(4) tetra-hedra or ZnO(5) trigonal bipyramids through common O atoms, leading to a three-dimensional framework structure. Some significant structural differences between the β-polymorph and the α-polymorph are discussed.

No MeSH data available.