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Poly[[μ(2)-aqua-tetraaquadi-μ(3)-malonato-nickel(II)strontium(II)] dihydrate].

Guo ML, Liu L, Lu CC - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: Inorg.The Sr(2+) ion is bonded to five O atoms from three different malonate dianions and four water mol-ecules, displaying a distorted tricapped trigonal-prismatic coordination geometry.This arrangement creates a metal-organic framework having a 20-membered ring with four Ni and six Sr atoms lying in the bc plane.

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Affiliation: School of Environment and Chemical Engineering and Key Laboratory of Hollow Fiber Membrane Materials & Membrane Processes, Tianjin Polytechnic University, Tianjin 300160, People's Republic of China.

ABSTRACT
The unit-cell parameters for the title mixed-metal coordination polymer, {[NiSr(C(3)H(2)O(4))(2)(H(2)O)(5)]·2H(2)O}(n), which is isostructural with its Co-containing analogue, were reported previously [Gil de Muro et al. (1999 ▶). Eur. J. Inorg. Chem. pp. 935-943]; the full crystal structure including a description of the hydrogen bonding is reported here. The Sr(2+) ion is bonded to five O atoms from three different malonate dianions and four water mol-ecules, displaying a distorted tricapped trigonal-prismatic coordination geometry. Two malonate dianions, two water mol-ecules and one Ni(2+) ion build up a dianionic [Ni(C(3)H(2)O(4))(2)(H(2)O)(2)](2-) unit incorporating a slightly distorted NiO(6) octa-hedron, which coordinates to three nearby Sr(2+) ions. This arrangement creates a metal-organic framework having a 20-membered ring with four Ni and six Sr atoms lying in the bc plane. The coordinated and uncoordinated water mol-ecules are responsible for the formation of two D5 hydrogen-bonded water chains within the 20-membered ring and they are linked into an R4 water cluster via two bifurcated O-H⋯(O,O) links.

No MeSH data available.


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The packing diagram of (I), showing hydrogen-bonding interactions between the [Ni(mal)2(H2O)2]2- dianions and water molecules, viewed down the c axis.
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Fap3: The packing diagram of (I), showing hydrogen-bonding interactions between the [Ni(mal)2(H2O)2]2- dianions and water molecules, viewed down the c axis.


Poly[[μ(2)-aqua-tetraaquadi-μ(3)-malonato-nickel(II)strontium(II)] dihydrate].

Guo ML, Liu L, Lu CC - Acta Crystallogr Sect E Struct Rep Online (2010)

The packing diagram of (I), showing hydrogen-bonding interactions between the [Ni(mal)2(H2O)2]2- dianions and water molecules, viewed down the c axis.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050271&req=5

Fap3: The packing diagram of (I), showing hydrogen-bonding interactions between the [Ni(mal)2(H2O)2]2- dianions and water molecules, viewed down the c axis.
Bottom Line: Inorg.The Sr(2+) ion is bonded to five O atoms from three different malonate dianions and four water mol-ecules, displaying a distorted tricapped trigonal-prismatic coordination geometry.This arrangement creates a metal-organic framework having a 20-membered ring with four Ni and six Sr atoms lying in the bc plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Environment and Chemical Engineering and Key Laboratory of Hollow Fiber Membrane Materials & Membrane Processes, Tianjin Polytechnic University, Tianjin 300160, People's Republic of China.

ABSTRACT
The unit-cell parameters for the title mixed-metal coordination polymer, {[NiSr(C(3)H(2)O(4))(2)(H(2)O)(5)]·2H(2)O}(n), which is isostructural with its Co-containing analogue, were reported previously [Gil de Muro et al. (1999 ▶). Eur. J. Inorg. Chem. pp. 935-943]; the full crystal structure including a description of the hydrogen bonding is reported here. The Sr(2+) ion is bonded to five O atoms from three different malonate dianions and four water mol-ecules, displaying a distorted tricapped trigonal-prismatic coordination geometry. Two malonate dianions, two water mol-ecules and one Ni(2+) ion build up a dianionic [Ni(C(3)H(2)O(4))(2)(H(2)O)(2)](2-) unit incorporating a slightly distorted NiO(6) octa-hedron, which coordinates to three nearby Sr(2+) ions. This arrangement creates a metal-organic framework having a 20-membered ring with four Ni and six Sr atoms lying in the bc plane. The coordinated and uncoordinated water mol-ecules are responsible for the formation of two D5 hydrogen-bonded water chains within the 20-membered ring and they are linked into an R4 water cluster via two bifurcated O-H⋯(O,O) links.

No MeSH data available.


Related in: MedlinePlus