Limits...
Aqua-{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II).

Suleiman Gwaram N, Ikmal Hisham NA, Khaledi H, Mohd Ali H - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title compound, [Ni(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N''-tridentate Schiff base, the N atoms of two thio-cyanate ligands and one water O atom in a distorted octa-hedral geometry.Intra-molecular C-H⋯N and C-H⋯O hydrogen bonds occur.In the crystal, O-H⋯S, O-H⋯O and C-H⋯S hydrogen bonds link adjacent mol-ecules into layers parallel to the ac plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
In the title compound, [Ni(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N''-tridentate Schiff base, the N atoms of two thio-cyanate ligands and one water O atom in a distorted octa-hedral geometry. Intra-molecular C-H⋯N and C-H⋯O hydrogen bonds occur. In the crystal, O-H⋯S, O-H⋯O and C-H⋯S hydrogen bonds link adjacent mol-ecules into layers parallel to the ac plane.

No MeSH data available.


Displacement ellipsoid plot of the title compound at the 30% probability level. Hydrogen atoms are drawn as spheres of arbitrary radii.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3050266&req=5

Fap1: Displacement ellipsoid plot of the title compound at the 30% probability level. Hydrogen atoms are drawn as spheres of arbitrary radii.


Aqua-{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II).

Suleiman Gwaram N, Ikmal Hisham NA, Khaledi H, Mohd Ali H - Acta Crystallogr Sect E Struct Rep Online (2010)

Displacement ellipsoid plot of the title compound at the 30% probability level. Hydrogen atoms are drawn as spheres of arbitrary radii.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050266&req=5

Fap1: Displacement ellipsoid plot of the title compound at the 30% probability level. Hydrogen atoms are drawn as spheres of arbitrary radii.
Bottom Line: In the title compound, [Ni(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N''-tridentate Schiff base, the N atoms of two thio-cyanate ligands and one water O atom in a distorted octa-hedral geometry.Intra-molecular C-H⋯N and C-H⋯O hydrogen bonds occur.In the crystal, O-H⋯S, O-H⋯O and C-H⋯S hydrogen bonds link adjacent mol-ecules into layers parallel to the ac plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
In the title compound, [Ni(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N''-tridentate Schiff base, the N atoms of two thio-cyanate ligands and one water O atom in a distorted octa-hedral geometry. Intra-molecular C-H⋯N and C-H⋯O hydrogen bonds occur. In the crystal, O-H⋯S, O-H⋯O and C-H⋯S hydrogen bonds link adjacent mol-ecules into layers parallel to the ac plane.

No MeSH data available.