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1,4-Bis(1H-benzimidazol-2-yl)benzene methanol monosolvate.

Su JB, Lin S, Chen LJ, Yang MX, Huang H - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The asymmetric unit of the title compound, C(20)H(14)N(4)·CH(4)O, contains two independent half-mol-ecules, each located on an inversion centre, and a methanol solvent mol-ecule.The benzimidazolyl groups form different dihedral angles [24.0 (1) and 11.6 (1)°] with the plane of the central benzene ring in the two mol-ecules.In the crystal, a two-dimensional network is formed through N-H⋯ N, N-H⋯O and O-H⋯N hydrogen-bonding inter-actions between the benzimidazole units and methanol solvent mol-ecules. π-π stacking inter-actions also occur between the benzimidazole rings of adjacent mol-ecules, with centroid-centroid distances of 3.720 (14) Å and inter-planar distances of 3.53 (1) Å .

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian 350007, People's Republic of China.

ABSTRACT
The asymmetric unit of the title compound, C(20)H(14)N(4)·CH(4)O, contains two independent half-mol-ecules, each located on an inversion centre, and a methanol solvent mol-ecule. The benzimidazolyl groups form different dihedral angles [24.0 (1) and 11.6 (1)°] with the plane of the central benzene ring in the two mol-ecules. In the crystal, a two-dimensional network is formed through N-H⋯ N, N-H⋯O and O-H⋯N hydrogen-bonding inter-actions between the benzimidazole units and methanol solvent mol-ecules. π-π stacking inter-actions also occur between the benzimidazole rings of adjacent mol-ecules, with centroid-centroid distances of 3.720 (14) Å and inter-planar distances of 3.53 (1) Å .

No MeSH data available.


Related in: MedlinePlus

A molecular drawing of (1), showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level.
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Fap1: A molecular drawing of (1), showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level.


1,4-Bis(1H-benzimidazol-2-yl)benzene methanol monosolvate.

Su JB, Lin S, Chen LJ, Yang MX, Huang H - Acta Crystallogr Sect E Struct Rep Online (2010)

A molecular drawing of (1), showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050263&req=5

Fap1: A molecular drawing of (1), showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level.
Bottom Line: The asymmetric unit of the title compound, C(20)H(14)N(4)·CH(4)O, contains two independent half-mol-ecules, each located on an inversion centre, and a methanol solvent mol-ecule.The benzimidazolyl groups form different dihedral angles [24.0 (1) and 11.6 (1)°] with the plane of the central benzene ring in the two mol-ecules.In the crystal, a two-dimensional network is formed through N-H⋯ N, N-H⋯O and O-H⋯N hydrogen-bonding inter-actions between the benzimidazole units and methanol solvent mol-ecules. π-π stacking inter-actions also occur between the benzimidazole rings of adjacent mol-ecules, with centroid-centroid distances of 3.720 (14) Å and inter-planar distances of 3.53 (1) Å .

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian 350007, People's Republic of China.

ABSTRACT
The asymmetric unit of the title compound, C(20)H(14)N(4)·CH(4)O, contains two independent half-mol-ecules, each located on an inversion centre, and a methanol solvent mol-ecule. The benzimidazolyl groups form different dihedral angles [24.0 (1) and 11.6 (1)°] with the plane of the central benzene ring in the two mol-ecules. In the crystal, a two-dimensional network is formed through N-H⋯ N, N-H⋯O and O-H⋯N hydrogen-bonding inter-actions between the benzimidazole units and methanol solvent mol-ecules. π-π stacking inter-actions also occur between the benzimidazole rings of adjacent mol-ecules, with centroid-centroid distances of 3.720 (14) Å and inter-planar distances of 3.53 (1) Å .

No MeSH data available.


Related in: MedlinePlus