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Butyl-trichlorido{2-[(diisopropyl-ammonio)-meth-yl]phen-yl}tin(IV) dichloro-methane monosolvate.

Rotar A, Varga RA, Staninska M - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The title compound, [Sn(C(4)H(9))(C(13)H(21)N)Cl(3)]·CH(2)Cl(2), was obtained by recrystallization of [2-(diisopropyl-amino-meth-yl)phen-yl]tin(IV) butyl dichloride from a CH(2)Cl(2)/n-hexane mixture (1:4 v/v) in the presence of ambient moisture.The N atom of the 2-[(diisopropyl-ammonio)-meth-yl]phenyl ligand forms a strong intra-molecular N-H⋯Cl hydrogen bond, resulting in a zwitterionic species, [2-((i)Pr(2)HN(+)CH(2))C(6)H(4)]SnBuCl(3) (-)·CH(2)Cl(2).Disorder was found in the n-butyl group, which was refined as disordered over three positions, with site occupancies of 0.22 (1), 0.51 (1) and 0.27 (2).

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Affiliation: Faculty of Chemistry and Chemical Engineering, Babes-Bolyai University, 11 Arany Janos St, RO-400028, Cluj Napoca, Romania.

ABSTRACT
The title compound, [Sn(C(4)H(9))(C(13)H(21)N)Cl(3)]·CH(2)Cl(2), was obtained by recrystallization of [2-(diisopropyl-amino-meth-yl)phen-yl]tin(IV) butyl dichloride from a CH(2)Cl(2)/n-hexane mixture (1:4 v/v) in the presence of ambient moisture. Partial hydrolysis led to the title compound, the hydro-chloric acid adduct of the dichloride, having a penta-coordinated Sn atom with a trigonal-bipyramidal C(2)SnCl(3) core. The N atom of the 2-[(diisopropyl-ammonio)-meth-yl]phenyl ligand forms a strong intra-molecular N-H⋯Cl hydrogen bond, resulting in a zwitterionic species, [2-((i)Pr(2)HN(+)CH(2))C(6)H(4)]SnBuCl(3) (-)·CH(2)Cl(2). Disorder was found in the n-butyl group, which was refined as disordered over three positions, with site occupancies of 0.22 (1), 0.51 (1) and 0.27 (2).

No MeSH data available.


View of the title compound showing the atom-numbering scheme and the intramolecular hydrogen bond (black dashed line) with only the major component for the disordered n-butyl group. Displacement ellipsoids are drawn at the 30% probability level and H atoms as spheres of arbitrary radii.
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Fap1: View of the title compound showing the atom-numbering scheme and the intramolecular hydrogen bond (black dashed line) with only the major component for the disordered n-butyl group. Displacement ellipsoids are drawn at the 30% probability level and H atoms as spheres of arbitrary radii.


Butyl-trichlorido{2-[(diisopropyl-ammonio)-meth-yl]phen-yl}tin(IV) dichloro-methane monosolvate.

Rotar A, Varga RA, Staninska M - Acta Crystallogr Sect E Struct Rep Online (2010)

View of the title compound showing the atom-numbering scheme and the intramolecular hydrogen bond (black dashed line) with only the major component for the disordered n-butyl group. Displacement ellipsoids are drawn at the 30% probability level and H atoms as spheres of arbitrary radii.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050250&req=5

Fap1: View of the title compound showing the atom-numbering scheme and the intramolecular hydrogen bond (black dashed line) with only the major component for the disordered n-butyl group. Displacement ellipsoids are drawn at the 30% probability level and H atoms as spheres of arbitrary radii.
Bottom Line: The title compound, [Sn(C(4)H(9))(C(13)H(21)N)Cl(3)]·CH(2)Cl(2), was obtained by recrystallization of [2-(diisopropyl-amino-meth-yl)phen-yl]tin(IV) butyl dichloride from a CH(2)Cl(2)/n-hexane mixture (1:4 v/v) in the presence of ambient moisture.The N atom of the 2-[(diisopropyl-ammonio)-meth-yl]phenyl ligand forms a strong intra-molecular N-H⋯Cl hydrogen bond, resulting in a zwitterionic species, [2-((i)Pr(2)HN(+)CH(2))C(6)H(4)]SnBuCl(3) (-)·CH(2)Cl(2).Disorder was found in the n-butyl group, which was refined as disordered over three positions, with site occupancies of 0.22 (1), 0.51 (1) and 0.27 (2).

View Article: PubMed Central - HTML - PubMed

Affiliation: Faculty of Chemistry and Chemical Engineering, Babes-Bolyai University, 11 Arany Janos St, RO-400028, Cluj Napoca, Romania.

ABSTRACT
The title compound, [Sn(C(4)H(9))(C(13)H(21)N)Cl(3)]·CH(2)Cl(2), was obtained by recrystallization of [2-(diisopropyl-amino-meth-yl)phen-yl]tin(IV) butyl dichloride from a CH(2)Cl(2)/n-hexane mixture (1:4 v/v) in the presence of ambient moisture. Partial hydrolysis led to the title compound, the hydro-chloric acid adduct of the dichloride, having a penta-coordinated Sn atom with a trigonal-bipyramidal C(2)SnCl(3) core. The N atom of the 2-[(diisopropyl-ammonio)-meth-yl]phenyl ligand forms a strong intra-molecular N-H⋯Cl hydrogen bond, resulting in a zwitterionic species, [2-((i)Pr(2)HN(+)CH(2))C(6)H(4)]SnBuCl(3) (-)·CH(2)Cl(2). Disorder was found in the n-butyl group, which was refined as disordered over three positions, with site occupancies of 0.22 (1), 0.51 (1) and 0.27 (2).

No MeSH data available.