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Bis(2-{2-[2-(benzyl-carbamo-yl)phen-oxy]acetamido}-eth-yl)ammonium nitrate ethanol disolvate.

Liu J, Tang X, Lu Z, Zhang G, Liu W - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: An O atom of the nitrate anion links the acidic H atoms of the cation via N-H⋯O hydrogen bonding.In addition, neighbouring cations are connected by inter-molecular N-H⋯O hydrogen bonds and π-π inter-actions between the benzamide groups of the cations [centroid-centroid distance = 4.000 (3) Å], forming a chain along [001].The ethanol solvent mol-ecules are arranged on the side of the chain through O-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

Affiliation: Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering and State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, People's Republic of China.

ABSTRACT
In the title compound, C(36)H(40)N(5)O(6) (+)·NO(3) (-)·2C(2)H(5)OH, the nitrate anion is disordered over the two orientations of equal occupancy while the solvent mol-ecule reveals large displacement parameters. The cation is formed by protonation of the N atom of a secondary amine in the middle of the flexible chain and the whole compound has crystallographically imposed C-2 symmetry with the crystallographic b axis. An O atom of the nitrate anion links the acidic H atoms of the cation via N-H⋯O hydrogen bonding. In addition, neighbouring cations are connected by inter-molecular N-H⋯O hydrogen bonds and π-π inter-actions between the benzamide groups of the cations [centroid-centroid distance = 4.000 (3) Å], forming a chain along [001]. The ethanol solvent mol-ecules are arranged on the side of the chain through O-H⋯O hydrogen bonds.

No MeSH data available.


The hydrogen bonded chain dominates the crystal packing. Hydrogen bonds are shown as turquiose dashed lines. H atoms not involved in hydrogen bonding have been omitted for clarity. The π···π interactions between benzamide groups are shown as light-blue dashed lines.
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Fap2: The hydrogen bonded chain dominates the crystal packing. Hydrogen bonds are shown as turquiose dashed lines. H atoms not involved in hydrogen bonding have been omitted for clarity. The π···π interactions between benzamide groups are shown as light-blue dashed lines.


Bis(2-{2-[2-(benzyl-carbamo-yl)phen-oxy]acetamido}-eth-yl)ammonium nitrate ethanol disolvate.

Liu J, Tang X, Lu Z, Zhang G, Liu W - Acta Crystallogr Sect E Struct Rep Online (2010)

The hydrogen bonded chain dominates the crystal packing. Hydrogen bonds are shown as turquiose dashed lines. H atoms not involved in hydrogen bonding have been omitted for clarity. The π···π interactions between benzamide groups are shown as light-blue dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050242&req=5

Fap2: The hydrogen bonded chain dominates the crystal packing. Hydrogen bonds are shown as turquiose dashed lines. H atoms not involved in hydrogen bonding have been omitted for clarity. The π···π interactions between benzamide groups are shown as light-blue dashed lines.
Bottom Line: An O atom of the nitrate anion links the acidic H atoms of the cation via N-H⋯O hydrogen bonding.In addition, neighbouring cations are connected by inter-molecular N-H⋯O hydrogen bonds and π-π inter-actions between the benzamide groups of the cations [centroid-centroid distance = 4.000 (3) Å], forming a chain along [001].The ethanol solvent mol-ecules are arranged on the side of the chain through O-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

Affiliation: Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering and State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, People's Republic of China.

ABSTRACT
In the title compound, C(36)H(40)N(5)O(6) (+)·NO(3) (-)·2C(2)H(5)OH, the nitrate anion is disordered over the two orientations of equal occupancy while the solvent mol-ecule reveals large displacement parameters. The cation is formed by protonation of the N atom of a secondary amine in the middle of the flexible chain and the whole compound has crystallographically imposed C-2 symmetry with the crystallographic b axis. An O atom of the nitrate anion links the acidic H atoms of the cation via N-H⋯O hydrogen bonding. In addition, neighbouring cations are connected by inter-molecular N-H⋯O hydrogen bonds and π-π inter-actions between the benzamide groups of the cations [centroid-centroid distance = 4.000 (3) Å], forming a chain along [001]. The ethanol solvent mol-ecules are arranged on the side of the chain through O-H⋯O hydrogen bonds.

No MeSH data available.